Molecules can be synthesized that adopt the three-dimensional geometry of every Platonic solid
Supramolecular chemistry and coordination-driven self-assembly have successfully synthesized complex cage structures and molecules that adopt the geometries of Platonic solids, such as icosahedra and octahedra.
The claim states that molecules can be synthesized that adopt the three-dimensional geometry of every Platonic solid. The retrieved literature clearly establishes that supramolecular chemistry, metal-organic frameworks, and coordination-driven self-assembly routinely produce molecules and cages mirroring Platonic solids (such as tetrahedra, octahedra, and icosahedra). Papers [0], [1], [2], and [7] provide explicit evidence of synthesizing structures with these precise geometries.
McTernan CT, Davies JA, Nitschke JR. Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.. 2022. https://doi.org/10.1021/acs.chemrev.1c00763
Discusses how metallosupramolecular chemistry forms self-assembled metal-organic architectures mimicking various polyhedral geometries.
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Olson AJ, Hu YH, Keinan E. Chemical mimicry of viral capsid self-assembly.. 2007. https://doi.org/10.1073/pnas.0709489104
Details the synthetic strategy for producing chemical capsids and structures with icosahedral symmetry, one of the Platonic solids.
Su YM, Wang Z, Schein S, Tung CH, Sun D. A Keplerian Ag<sub>90</sub> nest of Platonic and Archimedean polyhedra in different symmetry groups.. 2020. https://doi.org/10.1038/s41467-020-17198-1
Notes that coordination-driven self-assembly has created molecules mimicking Platonic, Archimedean, and other polyhedra.
Chen YS, Solel E, Huang YF, Wang CL, Tu TH, Keinan E, Chan YT. Chemical mimicry of viral capsid self-assembly via corannulene-based pentatopic tectons.. 2019. https://doi.org/10.1038/s41467-019-11457-6
Reports the successful synthesis of a giant icosahedral capsid via the self-assembly of tectons and metal cations.
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