Chemical reactivity changes under high voltage conditions
Chemical reactivity and stability are significantly altered under high-voltage or strong electric field conditions, as demonstrated across multiple electrochemical and quantum chemical studies.
The retrieved literature robustly confirms that electrical potentials, high-voltage conditions, and external electric fields alter reaction rates, pathway selectivity, interfacial stability, and bond characteristics. Multiple papers provide theoretical and experimental evidence supporting the claim.
Chang Liu, Yuye Li, Ting Chen, Shuyun Meng, Dong Liu, Daming Dong, Tianyan You. Electric Field-Induced Specific Preconcentration to Enhance DNA-Based Electrochemical Sensing of Hg2+ via the Synergy of Enrichment and Self-Cleaning.. 2022. https://doi.org/10.1021/acs.jafc.2c02416
Paper [0] shows that electric fields modulate electrochemical reactivity and binding interactions at interfaces.
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Alessandro Amadeo, Marco Francesco Torre, Klaudia Mráziková, F. Saija, S. Trusso, Jing Xie, M. Tommasini, G. Cassone. Hydrogen Bonds under Electric Fields with Quantum Accuracy. 2025. https://doi.org/10.1021/acs.jpca.5c01095
Paper [1] demonstrates that external electric fields alter hydrogen bond lengths, vibrational properties, and energetic behavior in chemical systems.
Francis M. Alcorn, Sajal Kumar Giri, Maya Chattoraj, Rachel Nixon, G. Schatz, P. Jain. Switching of electrochemical selectivity due to plasmonic field-induced dissociation. 2024. https://doi.org/10.1073/pnas.2404433121
Paper [4] illustrates that optically generated electric fields induce bond activation and alter electrochemical reaction selectivity.
Jang M, Kwon E, Jeon C, Kim S, Yu S. Interfacial Stability and Design Strategies for Halide Solid Electrolytes in High-Voltage All-Solid-State Sodium-Ion Batteries.. 2026. https://doi.org/10.1002/smtd.202502179
Paper [7] highlights interfacial chemical instability and decomposition reactions under high-voltage battery conditions.
Yue-Wen Zhou, Ming-Yang Jia, Jun-Lei Yang, Qinlei Liu, Zhen‐Feng Cai. Electric-field-induced covalent condensation of boronic acids in water microdroplets. 2025. https://doi.org/10.1039/d5sc01466b
Paper [9] provides experimental evidence that strong electric fields at microdroplet interfaces induce covalent condensation and alter reaction pathways.
Liu X, Jamadon NH, Yu Y, Zheng L, Tang R. Electrolyte design and interface engineering for high-voltage solid-state lithium batteries.. 2026. https://doi.org/10.3389/fchem.2026.1840199
Paper [10] details how high-voltage operation subjects solid electrolytes and interfaces to severe electrochemical oxidation and decomposition challenges.
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