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the claim

The pre-exponential factor in the Arrhenius equation depends on temperature

the verdict
SUPPORTED
the evidence backs this
Recorded sources
4 sources for · 0 against

Counts group repeated records of the same source within each side. They do not measure evidence strength or source independence.

Physical chemistry and materials science literature consistently demonstrate that the pre-exponential factor in the Arrhenius equation can exhibit temperature dependence, often manifesting through compensation effects or complex multi-step reaction kinetics.

The analysis

The retrieved literature contains multiple studies investigating temperature-dependent Arrhenius parameters where the pre-exponential factor varies or is modeled as a function of temperature. There are no refuting papers.

Evidence for · 4
The study of viscosity-temperature dependence and activation energy for palm oil and soybean oil
Recorded source metadata

E. Ike. The study of viscosity-temperature dependence and activation energy for palm oil and soybean oil. 2019. https://doi.org/10.4314/gjpas.v25i2.11

Paper 0 explicitly models the relationship between Arrhenius parameters, including temperature and the pre-exponential factor.

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More for · 3
Temperature dependence of Ge2Sb2Te5 conductivity and its change during aging
Recorded source metadata

Y. Vorobyov, A. Yakubov, A. Ermachikhin. Temperature dependence of Ge2Sb2Te5 conductivity and its change during aging. 2020. https://doi.org/10.1088/1757-899X/889/1/012032

Paper 1 interprets changes in conductivity through an Arrhenius model where both the activation energy and pre-exponential factor exhibit temperature dependence.

Compensation effects between the apparent activation energy and pre-exponential factor in simple models of electrocatalytic hydrogen evolution.
Recorded source metadata

Fingerhut J, Snitkoff-Sol RZ, Albers M, Vos RE, van der Heijden O, Koper MTM. Compensation effects between the apparent activation energy and pre-exponential factor in simple models of electrocatalytic hydrogen evolution.. 2026. https://doi.org/10.1039/d5fd00163c

Paper 3 analyzes temperature-dependent electrocatalytic kinetics that yield apparent compensation effects linking the pre-exponential factor to thermal variations.

Pressure and bias dependence of the rate-limiting steps of the oxygen reduction reaction.
Recorded source metadata

Silva Olaya AR, Druce J, Gisbert-Gonzalez JM, Ortega E, Roldan Cuenya B, Oener SZ. Pressure and bias dependence of the rate-limiting steps of the oxygen reduction reaction.. 2025. https://doi.org/10.1038/s41467-025-67494-x

Paper 4 performs bias- and temperature-dependent Arrhenius analyses showing how apparent activation energies and pre-exponential factors shift across rate-limiting steps.

The paper trail · every fact has a biography
first checked01 Aug 2026
judged → SUPPORTED · 8301 Aug 2026
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