Specific thermodynamic and structural factors determine the water of crystallisation in salts
Specific thermodynamic conditions and structural configurations, such as hydrogen bonding and coordination geometry, critically determine the presence and behavior of water of crystallisation in salts.
The retrieved literature consistently supports the claim that water of crystallisation and hydrate formation are governed by precise thermodynamic parameters, chemical bonding, and structural factors across various salt systems.
Kebede GG, Franco R, Izquierdo-Ruiz F, Lobato A, Recio JM. A Chemical Bonding Interpretation of Unusual Compressibility Trends in Hydrated Magnesium Sulfates.. 2025. https://doi.org/10.1021/acs.inorgchem.5c01765
The study on hydrated magnesium sulfates demonstrates that specific coordination and structural factors dictate crystal properties like compressibility and hydration states.
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Long A, Powell M, Dickey A, McMillen C, Kolis J. Maus's salts: an old family of iron sulfates with possible magnetic frustration.. 2026. https://doi.org/10.1107/s2052520626002027
Investigations into Maus's salts highlight how alkali cations and structural water configurations govern the formation and stability of these complex iron sulfate hydrates.
Carmona-Sepúlveda IP, Kerenick AR, Fenton JL. Solvent-induced structural and optical transformations in a hybrid copper phosphate framework.. 2026. https://doi.org/10.1039/d6ce00295a
Research on hybrid copper phosphate frameworks shows how specific solvent environments and hydrogen-bonding coordination geometry drive structural transformations related to hydration.
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