The Schrödinger equation works for the hydrogen atom despite relativistic nuclear boundaries
The Schrödinger equation successfully models the hydrogen atom, with relativistic boundary and potential effects adequately captured through perturbation theory or modified relativistic corrections.
The retrieved literature confirms that standard quantum mechanical and QED treatments of atomic hydrogen successfully account for relativistic effects while utilizing frameworks rooted in the Schrödinger equation, yielding highly accurate predictions that match experimental spectroscopy.
Maisenbacher L, Wirthl V, Matveev A, Grinin A, Pohl R, Hänsch TW, Udem T. Sub-part-per-trillion test of the Standard Model with atomic hydrogen.. 2026. https://doi.org/10.1038/s41586-026-10124-3
High-precision atomic hydrogen spectroscopy confirms that standard non-relativistic and bound-state Schrödinger-based QED methods predict transition frequencies with extreme accuracy.
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Amaro MB, Nazeef, Dussech CJ, Qi C. Closed-form spin-relativistic corrections from the Dirac equation enabling a modified Schrödinger solver.. 2025. https://doi.org/10.1038/s41598-025-29243-4
Derivations from the Dirac equation confirm that Schrödinger-like solvers can successfully retain leading relativistic corrections for Coulomb potentials.
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