Stainlessness is a bulk material property rather than a purely surface property of stainless steel
Stainless steel's corrosion resistance is fundamentally determined by its bulk chemical composition, such as chromium and molybdenum content, showing that stainlessness relies heavily on bulk material properties.
The retrieved papers consistently emphasize that the corrosion resistance, pitting behavior, and overall performance of stainless steels are strongly dictated by their bulk alloy composition (e.g., chromium, molybdenum, and sulfur levels), thereby supporting the claim that stainlessness is tied to bulk material properties.
C.S. Brossia, R.G. Kelly. Influence of Alloy Sulfur Content and Bulk Electrolyte Composition on Crevice Corrosion Initiation of Austenitic Stainless Steel. 1998. https://doi.org/10.5006/1.3284838
Paper [0] demonstrates that bulk alloy composition (such as sulfur content and molybdenum levels) significantly influences the corrosion initiation behavior of stainless steel.
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P.I. Marshall, T.G. Gooch. Effect of Composition on Corrosion Resistance of High-Alloy Austenitic Stainless Steel Weld Metals. 1993. https://doi.org/10.5006/1.3316080
Paper [1] shows that bulk alloying elements like chromium, molybdenum, and nitrogen directly determine the pitting resistance and corrosion performance of stainless steel.
Sukanya Hägg Mameng, Rachel Pettersson, Christofer Leygraf. Effect of Stainless Steel Composition on Atmospheric Corrosion Resistance at a Marine Site in Dubai. 2017. https://doi.org/10.5006/2372
Paper [2] finds that both bulk chromium and molybdenum content and the surface passive film correlate with atmospheric corrosion resistance, highlighting the integral role of bulk material properties.
P I Marshall, T G Gooch. Effect of Composition on Corrosion Resistance of High Alloy Austenitic Stainless Steel Weld Metals. 1992. https://doi.org/10.5006/c1992-92296
Paper [5] confirms that the overall composition of the stainless steel alloy governs its corrosion resistance and pitting behavior.
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