Alkanes undergo isomerization under Lewis acidic conditions via carbenium ion intermediates.
Alkanes undergo isomerization under acidic conditions through mechanisms involving carbenium ion intermediates, as supported by catalytic studies and theoretical models.
The claim states that alkanes undergo isomerization under Lewis acidic conditions via carbenium ion intermediates. Papers [3] and [5] directly support aspects of acid-catalyzed alkane reactions and the stabilization of carbenium ion intermediates. The retrieved literature aligns with established organic chemistry principles regarding alkane isomerization.
S. M. Izan, S. Triwahyono, A. A. Jalil, Z. A. Majid, N. Fatah, M. Hamid, M. Ibrahim. Additional Lewis acid sites of protonated fibrous silica@BEA zeolite (HSi@BEA) improving the generation of protonic acid sites in the isomerization of C6 alkane and cycloalkanes. 2019. https://doi.org/10.1016/J.APCATA.2018.11.028
Paper [3] discusses how Lewis acid sites and protonic acid sites facilitate alkane isomerization processes.
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Shuo Li, Jian-lin Cao, Yu Dang, Xiang Feng, Yibin Liu, Xiaobo Chen, Chaohe Yang. Understanding the Effect of Acid Strength on the Alkane-Alkoxide Hydride Transfer Reaction over Solid Acid Catalysts: Insights from Density Functional Theory. 2019. https://doi.org/10.1021/ACS.IECR.9B01125
Paper [5] explains via density functional theory how acid strength stabilizes carbenium ions as key intermediates in hydrocarbon transformations.
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