Changes in iron oxidation state as magma rises are driven by degassing and fractional crystallization
Multiple petrological and thermodynamic studies support the conclusion that changes in iron oxidation state during magma ascent and evolution are driven by a combination of degassing and fractional crystallization.
The claim specifies that iron oxidation state changes during magma rise are driven by degassing and fractional crystallization. Papers [0], [2], and [3] explicitly discuss how ascent-driven degassing and fractional crystallization processes control oxygen fugacity and iron/sulfur redox states in magmatic systems. No papers refute this well-established petrological mechanism.
S. Ding, T. Plank, P. Wallace, D. Rasmussen. Sulfur_X: A Model of Sulfur Degassing During Magma Ascent. 2023. https://doi.org/10.1029/2022GC010552
Demonstrates that degassing processes during magma ascent track and drive changes in iron and sulfur redox states.
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E. Gennaro, A. Paonita, G. Iacono-Marziano, Yves Moussallam, M. Pichavant, N. Peters, C. Martel. Sulphur behaviour and redox conditions in etnean magmas during magma differentiation and degassing. 2020. https://doi.org/10.1093/petrology/egaa095
Shows that magma differentiation and fractional crystallization, coupled with degassing, significantly alter oxygen fugacity and iron/sulfur behavior.
Tang M, Erdman M, Eldridge G, Lee CA. The redox "filter" beneath magmatic orogens and the formation of continental crust.. 2018. https://doi.org/10.1126/sciadv.aar4444
Indicates that fractional crystallization (such as of garnet) causes simultaneous oxidation and iron depletion in ascending or differentiating magmas.
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