Paper becomes weaker and more fragile when wet due to hydrogen bond disruption
Paper and cellulose-based materials lose strength and structural integrity when exposed to moisture due to the interaction of water with the material's hydrogen-bonding network.
The retrieved literature consistently supports the widely established scientific consensus that unmodified cellulosic paper and fibers lose mechanical strength and become fragile when wet due to water disrupting internal hydrogen bonds and interacting strongly with hydroxyl groups.
Qingbo Wang, Haishun Du, Fang Zhang, Yuedong Zhang, Meiyan Wu, Guang Yu, Chao Liu, Bin Li, Hui Peng. Flexible cellulose nanopaper with high wet tensile strength, high toughness and tunable ultraviolet blocking ability fabricated from tobacco stalk via a sustainable method. 2018. https://doi.org/10.1039/C8TA01986J
The paper notes that cellulose nanopaper is typically sensitive to water, resulting in a significant loss of strength and durability.
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Cong Jiang, Jiaming Wu, Hong Wang, Yehan Tao, Jie Lu, Jinwen Hu, Jian Du, Haisong Wang. Multiple cross-linked cellulosic paper-based waterproof and biodegradable mulch film for "green" agriculture.. 2024. https://doi.org/10.1016/j.ijbiomac.2024.137977
The paper states that the highly hydrophilic property and poor wet strength of cellulose restrict its practical application without hydrophobic modifications.
Kudzin MH, Mrozińska Z, Chruściel JJ, Olczyk J, Sikora M, Sulak E, Walawska A. Chemical Modification of Cellulose Fibers for Sustainable Food Packaging: Structure-Property-Sustainability Relationships.. 2026. https://doi.org/10.3390/ma19061124
The review explains that the strong binding of water to hydroxyl groups in cellulose causes dimensional instability and compromises barrier performance.
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