Aziridinylmethyl and oxiranylmethyl radicals undergo ring-opening reactions

the verdict

SUPPORTED

the evidence backs this

Recorded sources

3 sources for · 0 against

Counts group repeated records of the same source within each side. They do not measure evidence strength or source independence.

Both experimental and theoretical studies demonstrate that aziridinylmethyl and oxiranylmethyl radicals readily undergo ring-opening reactions, with the regiochemistry strongly influenced by substituent effects.

The analysis

All retrieved papers explicitly discuss and confirm the ring-opening reactions of either oxiranylmethyl or aziridinylmethyl radicals, providing both kinetic data and theoretical analyses for these rearrangements.

Evidence for · 3

Radical reactions of epoxides. 2. intramolecular competition between cyclopropylmethyl and oxiranylmethyl radical ring‐opening rearrangements

Recorded source metadata

Kevin W. Krosley, Gerald Jay Gleicher. Radical reactions of epoxides. 2. intramolecular competition between cyclopropylmethyl and oxiranylmethyl radical ring‐opening rearrangements. 1993. https://doi.org/10.1002/poc.610060406

Demonstrates that oxiranylmethyl radicals undergo ring-opening rearrangements with a rapid rate.

Source citation format

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More for · 2

Substituent effects on the ring opening of 2-aziridinylmethyl radicals.

Recorded source metadata

Wang YM, Fu Y, Liu L, Guo QX. Substituent effects on the ring opening of 2-aziridinylmethyl radicals.. 2005. https://doi.org/10.1021/jo048068a

Systematically studies and confirms the ring-opening reactions of 2-aziridinylmethyl radicals and their substituent effects.

Source citation format

ChemInform Abstract: Substituent Control over the Regiochemistry of Ring Opening of 2‐ Aziridinylmethyl Radicals.

Recorded source metadata

A. L. SCHWAN, M. D. REFVIK. ChemInform Abstract: Substituent Control over the Regiochemistry of Ring Opening of 2‐ Aziridinylmethyl Radicals.. 1993. https://doi.org/10.1002/chin.199341106

Provides further chemical information supporting the regiochemistry and occurrence of ring-opening in 2-aziridinylmethyl radicals.

Source citation format

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first checked01 Aug 2026

judged → SUPPORTED · 8401 Aug 2026

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