Alkaline and acidified potassium permanganate function differently as oxidizing agents
Potassium permanganate acts differently as an oxidizing agent depending on whether it is in an acidic or alkaline medium, as its oxidation potential, reaction kinetics, and degradation pathways vary substantially with pH.
The retrieved papers separately detail the distinct kinetic behaviors, reaction mechanisms, and oxidation potentials of potassium permanganate under acidic (e.g., Paper 0) versus alkaline (e.g., Paper 1) conditions, while Paper 6 explicitly highlights how pH shifts alter its oxidation potential and degradation pathways.
S. Ibrahim, A. Al-Hossainy. Kinetics and mechanism of oxidation of bromothymol blue by permanganate ion in acidic medium: Application to textile industrial wastewater treatment. 2020. https://doi.org/10.1016/j.molliq.2020.114041
Paper 0 examines potassium permanganate functioning specifically as an oxidizing agent in an acidic medium.
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S. F., Luz Clarita. On the organic/inorganic mechanism of the oxidation of uric acid by means of potassium permanganate in alkaline medium. 2026. https://doi.org/10.56781/ijsrcp.2026.6.2.0014
Paper 1 investigates the specific organic/inorganic oxidation mechanism of potassium permanganate operating in an alkaline medium.
Yaqiong Dong, Yufeng Wang, Lantian Xing, Ghufran Uddin, Yuanxiao Guan, Zhengyang E, Jianjun Liang, Ping Li, Changjie Liu, Qiaohui Fan. Stable Carbon Isotope Fractionation of Trichloroethylene Oxidized by Potassium Permanganate Under Different Environmental Conditions. 2025. https://doi.org/10.3390/app15137142
Paper 6 notes that the oxidation potential and degradation pathways of potassium permanganate change significantly across different pH levels from acidic to alkaline conditions.
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