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the claim

Hydrogen fluoride is classified as a covalently bonded compound with strong intermolecular hydrogen bonding

the verdict
SUPPORTED
the evidence backs this
Recorded sources
4 sources for · 0 against

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Hydrogen fluoride exhibits strong intermolecular hydrogen bonding and covalently bonded structural characteristics, as confirmed by theoretical calculations and crystal structure analyses.

The analysis

The retrieved papers consistently support the chemical description of hydrogen fluoride (HF) possessing covalent bonding alongside exceptionally strong intermolecular hydrogen-bonding characteristics (such as in crystal chains and complexes).

Evidence for · 4
Structure features of hydrogen bonding and their signatures in vibrational dynamics
Recorded source metadata

Yu. V. Novakovskaya. Structure features of hydrogen bonding and their signatures in vibrational dynamics. 2020. https://doi.org/10.17725/rensit.2020.12.049

Simulations of molecular clusters including hydrogen fluoride highlight the electronic-structure peculiarities and vibrational dynamics of hydrogen bonding in HF.

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More for · 3
Isotope effect on hydrogen bond symmetrization in hydrogen and deuterium fluoride crystals by molecular dynamics simulation.
Recorded source metadata

Hichem Dammak, Fabien Brieuc, Grégory Geneste, Marc Torrent, Marc Hayoun. Isotope effect on hydrogen bond symmetrization in hydrogen and deuterium fluoride crystals by molecular dynamics simulation.. 2019. https://doi.org/10.1039/c8cp06949b

Studies on hydrogen fluoride crystals demonstrate the presence of strong intermolecular hydrogen bonds within planar zigzag chains.

Hydrogen bonding interactions in PN...HX complexes: DFT and ab initio studies of structure, properties and topology.
Recorded source metadata

Pradeep Risikrishna Varadwaj. Hydrogen bonding interactions in PN...HX complexes: DFT and ab initio studies of structure, properties and topology.. 2010. https://doi.org/10.1007/s00894-009-0603-1

Calculations on HX complexes confirm that hydrogen fluoride forms strong hydrogen-bonded structures with significant electrostatic and covalent contributions.

In Situ Measure of Intrinsic Bond Strength in Crystalline Structures: Local Vibrational Mode Theory for Periodic Systems.
Recorded source metadata

Yunwen Tao, Wenli Zou, Daniel Sethio, Niraj Verma, Yue Qiu, Chuan Tian, Dieter Cremer, Elfi Kraka. In Situ Measure of Intrinsic Bond Strength in Crystalline Structures: Local Vibrational Mode Theory for Periodic Systems.. 2019. https://doi.org/10.1021/acs.jctc.8b01279

Local vibrational mode analysis applied to periodic systems specifically examines hydrogen fluoride chains to characterize their intrinsic bond strength.

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first checked31 Jul 2026
judged → SUPPORTED · 7531 Jul 2026
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