Molecules with axial chirality contain stereogenic units
Molecules exhibiting axial chirality are characterized by the presence of a stereogenic unit, specifically a stereogenic axis.
The retrieved literature consistently treats axial chirality as a form of stereoisomerism defined by a stereogenic axis acting as a stereogenic unit.
Goldup SM. The End of the Beginning of Mechanical Stereochemistry.. 2024. https://doi.org/10.1021/acs.accounts.4c00195
Discusses the stereochemical framework of stereogenic units, including those associated with mechanical and axial chirality.
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Meraviglia S, Romanelli A, Iannelli P, Rizzato S, Contini A, Abbiati G, Pirovano V. Atroposelective construction of indole-fused diazocines <i>via</i> gold(i)-catalysed 8-<i>endo</i>-dig cyclisation.. 2026. https://doi.org/10.1039/d6sc00020g
Examines axially chiral molecules possessing stereogenic axes as part of their structural features.
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