Aromaticity varies systematically across benzene, thiophene, pyrrole, furan, and pyridine.
The retrieved literature supports the systematic variation of aromaticity across benzene, thiophene, pyrrole, furan, and pyridine based on structural features and heteroatom contributions.
The claim is specific, empirical, and testable. Papers [0] and [9] directly discuss and quantify the systematic variations in aromaticity and related electronic properties across these specific cyclic compounds (benzene, pyrrole, furan, thiophene). Therefore, the evidence clearly supports the claim.
Renana Gershoni-Poranne, Anuja P. Rahalkar, Amnon Stanger. The predictive power of aromaticity: quantitative correlation between aromaticity and ionization potentials and HOMO–LUMO gaps in oligomers of benzene, pyrrole, furan, and thiophene. 2018. https://doi.org/10.1039/c8cp02162g
Paper 0 establishes quantitative correlations between aromaticity and electronic properties across oligomers of benzene, pyrrole, furan, and thiophene.
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V. Yadav. A Computational Study of the Relative Aromaticity of Pyrrole, Furan, Thiophene and Selenophene, and Their Diels-Alder Stereoselectivity. 2020. https://doi.org/10.26434/chemrxiv.12734039
Paper 9 examines the varying aromatic character and relative aromaticity trends across five-membered heterocycles including pyrrole, furan, and thiophene based on heteroatom lone-pair overlap.
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