Complex ions exhibit thermochromism due to temperature-dependent changes in ligand field splitting and population of electronic states.
Complex ions and metal complexes frequently exhibit thermochromism driven by temperature-dependent variations in electronic states, ligand fields, and associated charge-transfer processes.
The retrieved literature supports the well-established chemical principle that thermochromism in complex ions or coordination polymers arises from temperature-dependent variations in electronic structures, such as spin-crossover, ligand field splitting, and intermetallic charge transfer. Papers [0] and [1] directly confirm that such optical changes in metal complexes are linked to electronic state shifts.
Zakrzewski JJ, Liberka M, Wang J, Chorazy S, Ohkoshi SI. Optical Phenomena in Molecule-Based Magnetic Materials.. 2024. https://doi.org/10.1021/acs.chemrev.3c00840
Paper [0] discusses the optical phenomena of molecule-based magnetic materials, noting that metal complexes exhibit thermochromism tied to electronic state transitions.
See more details
Getzner L, Paliwoda D, Vendier L, Lawson-Daku LM, Rotaru A, Molnár G, Cobo S, Bousseksou A. Combining electron transfer, spin crossover, and redox properties in metal-organic frameworks.. 2024. https://doi.org/10.1038/s41467-024-51385-8
Paper [1] demonstrates that metal-organic frameworks containing metal complexes exhibit vivid thermochromism driven by temperature-dependent electronic spin state changes and electron transfer.
The paper trail · every fact has a biography
Challenge the receipt
Citation formatting by citeproc-js (Frank Bennett) and the Citation Style Language project. Source and licenses.
Terms · Privacy · How verdicts work · Dispute this receipt