The cis isomer dipole moment is always greater than the trans isomer dipole moment
Is it true that the cis isomer dipole moment is always greater than the trans isomer dipole moment?
No. The claim that the cis isomer dipole moment is always greater than the trans isomer is refuted by chemical data showing that trans isomers frequently possess larger dipole moments than their corresponding cis counterparts.
Verdict: REFUTED · 0 sources for, 2 against · Last checked
The claim states an absolute rule ("is always greater") regarding the relative dipole moments of cis and trans isomers. Multiple retrieved experimental chemistry papers (e.g., [0] and [3]) provide clear counterexamples where the trans isomer has a larger dipole moment than the cis isomer (e.g., cyclopropanecarboxaldehyde and 1,3-pentadiene). Therefore, the claim is definitively refuted by the provided evidence.
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Volltrauer, H. N. & Schwendeman, R. H. (1971). Microwave Spectra, Dipole Moments, and Torsional Potential Constants of <i>cis</i>- and <i>trans</i>-Cyclopropanecarboxaldehyde. doi.org. https://doi.org/10.1063/1.1674602
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Hsu, S. L. & Flygare, W. H. (1970). Microwave Spectra, Barriers to Internal Rotation of the Methyl Group, and Molecular Electrical Dipole Moments in <i>trans</i>- and <i>cis</i>-1,3-Pentadiene. doi.org. https://doi.org/10.1063/1.1673098
- Is it true that Cis-but-2-ene and trans-but-2-ene have different boiling and melting points? COMMON KNOWLEDGE
- Is it true that pyrrole and furan possess specific and measurable dipole moments? SUPPORTED
- Is it true that the electric dipole moment vector points from the negative charge to the positive charge? SUPPORTED
What does the evidence say?
The claim states an absolute rule ("is always greater") regarding the relative dipole moments of cis and trans isomers. Multiple retrieved experimental chemistry papers (e.g., [0] and [3]) provide clear counterexamples where the trans isomer has a larger dipole moment than the cis isomer (e.g., cyclopropanecarboxaldehyde and 1,3-pentadiene). Therefore, the claim is definitively refuted by the provided evidence.
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