Reactions between species with different total electron spin multiplicities are spin-forbidden
Is it true that reactions between species with different total electron spin multiplicities are spin-forbidden?
Yes. Chemical reactions and transitions between species possessing different total electron spin multiplicities are fundamentally spin-forbidden, requiring mechanisms such as spin-orbit coupling or intersystem crossing to proceed.
Verdict: SUPPORTED · 3 sources for, 0 against · Last checked
The retrieved literature consistently supports the fundamental premise in quantum chemistry and reaction dynamics that reactions or transitions involving a change in total electron spin multiplicity (e.g., between singlet and triplet states) are spin-forbidden and typically necessitate spin-orbit coupling or intersystem crossing to occur.
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X, Z., T, W., YQ, G., & Y, X. (2025). Noncollinear Spin-Flip TDDFT for Potential Energy Surface Crossings: Conical Intersections and Spin Crossings.. doi.org. https://doi.org/10.1021/acs.jctc.5c01272
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Y, W., W, Q., Y, Y., & J, M. (2026). Electron transfer drives hydroxyl radical formation in peroxone reactions.. doi.org. https://doi.org/10.1016/j.ese.2026.100704
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TWR, L., AA, V., SG, A., & NS, S. (2026). Kinetics of Submerged Intersystem Crossings in Strongly Coupled Ion-Molecule Reactions: I<sup>+</sup> + CH<sub>3</sub>X (X = F, Cl, Br, I).. doi.org. https://doi.org/10.1021/acs.jpca.6c00949
What does the evidence say?
The retrieved literature consistently supports the fundamental premise in quantum chemistry and reaction dynamics that reactions or transitions involving a change in total electron spin multiplicity (e.g., between singlet and triplet states) are spin-forbidden and typically necessitate spin-orbit coupling or intersystem crossing to occur.
- Are reactions between species with different total electron spin multiplicities spin-forbidden?
- Is it true that reactions involving species with differing total electron spin multiplicities are spin-forbidden?
- Do reactions between species having different total electron spin multiplicities count as spin-forbidden?
- Is the claim that reactions between species with different total electron spin multiplicities are spin-forbidden correct?
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