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the claim

Phase change entropy can be calculated using vaporization enthalpy and boiling point.

the verdict
SUPPORTED
the evidence backs this
Recorded sources
2 sources for · 0 against

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Is it true that phase change entropy can be calculated using vaporization enthalpy and boiling point?

Yes. Phase change entropy (specifically vaporization entropy) is closely related to and can be derived from the vaporization enthalpy and the boiling point, as established by thermodynamic relationships like Trouton's rule and its extensions.

Verdict: SUPPORTED · 2 sources for, 0 against · Last checked

The analysis

The claim states that phase change entropy can be calculated using vaporization enthalpy and boiling point. From thermodynamics, the entropy of vaporization at the boiling point is approximately equal to the enthalpy of vaporization divided by the boiling point (Delta S = Delta H / T_b), a principle underlying rules like Trouton's and Hildebrand's. Retrieved papers [7] and [9] explicitly analyze and utilize data connecting vaporization enthalpy, boiling temperature, and vaporization entropy.

Evidence for · 2
1983
Discusses the calculation and relationship of the entropy of vaporization at the boiling point relative to temperature and vapor volume.
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Shinoda, K. (1983). Entropy of vaporization at the boiling point. doi.org. https://doi.org/10.1063/1.445282

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More for · 1
2020
Analyzes systematic correlations between the enthalpy of evaporation and boiling temperature to determine the entropy of evaporation across hundreds of materials.
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Mehling, H. (2020). Enthalpy, entropy, and temperature of the phase change liquid-gas – An analysis of data of 719 materials regarding systematic correlations. doi.org. https://doi.org/10.32908/hthp.v48.624

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also asked as
  • Can vaporization enthalpy and boiling point be used to calculate phase change entropy?
  • Is it possible to find phase change entropy from the boiling point and vaporization enthalpy?
  • Do you calculate phase change entropy using vaporization enthalpy and boiling point?
  • Can you determine phase change entropy using the boiling point and heat of vaporization?
Receipt History
first checked04 Aug 2026
judged → SUPPORTED · 8104 Aug 2026
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