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the claim

Bonding and anti-bonding orbitals exist for ionic bonds

the verdict
SUPPORTED
the evidence backs this
Recorded sources
3 sources for · 0 against

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Is it true that bonding and anti-bonding orbitals exist for ionic bonds?

Yes. Modern computational chemistry demonstrates that bonds traditionally classified as ionic frequently possess partial covalent character, involving overlapping atomic orbitals that form bonding and antibonding molecular orbitals.

Verdict: SUPPORTED · 3 sources for, 0 against · Last checked

The analysis

Although ionic bonding is classically viewed purely through electrostatic attraction, advanced quantum chemical studies (such as DFT and NBO analyses) regularly evaluate ionic bonds for covalent contributions, revealing that molecular orbital descriptions incorporating bonding and anti-bonding orbitals apply across various systems traditionally termed ionic.

Evidence for · 3
2022
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Eroshin, A. V., Otlyotov, A. A., Kuzmin, I., Stuzhin, P., & Zhabanov, Y. A. (2022). DFT Study of the Molecular and Electronic Structure of Metal-Free Tetrabenzoporphyrin and Its Metal Complexes with Zn, Cd, Al, Ga, In. doi.org. https://doi.org/10.3390/ijms23020939

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More for · 2
2019
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Duan, M., Li, P., Zhao, H., Xie, F., & Ma, J. (2019). Organic Compounds of Actinyls: Systematic Computational Assessment of Structural and Topological Properties in [AnO2(C2O4) n](2 n-2)- (An = U, Np, Pu, Am; n = 1-3) Complexes.. doi.org. https://doi.org/10.1021/acs.inorgchem.8b03538

2021
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Jiang, Y., Wu, Y., Deng, J., & Wang, Z. (2021). Antiaromaticity-aromaticity transition of cyclo[16]carbon upon metal encapsulation.. doi.org. https://doi.org/10.1039/d0cp06256a

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What does the evidence say?

Although ionic bonding is classically viewed purely through electrostatic attraction, advanced quantum chemical studies (such as DFT and NBO analyses) regularly evaluate ionic bonds for covalent contributions, revealing that molecular orbital descriptions incorporating bonding and anti-bonding orbitals apply across various systems traditionally termed ionic.

Receipt History
first checked04 Aug 2026
judged → SUPPORTED · 8404 Aug 2026
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