Allenes are capable of forming ring structures
Is it true that Allenes are capable of forming ring structures?
Yes. Multiple studies demonstrate that allenes readily participate in diverse cyclization and cycloaddition reactions to form various ring structures.
Verdict: SUPPORTED · 8 sources for, 0 against · Last checked
The retrieved papers consistently show that allenes can act as versatile intermediates in cyclization, annulation, and cycloaddition reactions, successfully forming various fused, medium-sized, and heterocyclic ring structures.
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Ikeuchi, T., Inuki, S., Oishi, S., & Ohno, H. (2019). Gold(I)-Catalyzed Cascade Cyclization Reactions of Allenynes for the Synthesis of Fused Cyclopropanes and Acenaphthenes.. doi.org. https://doi.org/10.1002/anie.201903384
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Saha, R., Chatterjee, A., Mondal, S., Pal, P., Chakrabarty, K., & Das, G. (2019). Comparative DFT study on the platinum catalyzed [3 + 2] and [2 + 2] cycloaddition reactions between the derivatives of allene and alkene. doi.org. https://doi.org/10.1016/J.COMPTC.2019.112507
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Zhao, H., Jiang, Y., Zhang, J., Pu, Y., Zeng, S., Ni, B., Shang, Y., & Wang, J. (2025). Construction of Eight-Membered N-Heterocycles via Palladium-Catalyzed Cyclization of Allenyl Isocyanides.. doi.org. https://doi.org/10.1021/acs.orglett.5c02371
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AC, T., H, X., B, G., & JS, D. (2026). Alkyne Cyclizations through Vinyl Cations and Stereoselective Allene Formation by Terpene Synthases.. doi.org. https://doi.org/10.1021/jacs.6c05306
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SH, S., SN, Y., H, L., ZY, D., Y, J., XP, H., & QA, C. (2026). Phosphine-Catalyzed Unsymmetric [2 + 2] Annulation of Allenyl Phosphonates for Highly Substituted Cyclobutenes.. doi.org. https://doi.org/10.1002/anie.7982002
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J, H., MS, B., C, K., & T, B. (2026). Photochemical Cyclization of Tertiary Buta-2,3-dienamides to β-Lactams Upon Triplet Energy Transfer.. doi.org. https://doi.org/10.1002/anie.202525347
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H, S., DK, B., H, S., & J, W. (2026). Alcohol-Directed Carboamination of Conjugated Enynes.. doi.org. https://doi.org/10.1002/anie.6963888
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L, O., J, Z., N, S., & T, B. (2026). Dearomatization of Aromatic Carbonyl Compounds by Photocycloaddition Reactions to 1,1-Dimethylallene.. doi.org. https://doi.org/10.1021/acs.orglett.6c00429
What does the evidence say?
The retrieved papers consistently show that allenes can act as versatile intermediates in cyclization, annulation, and cycloaddition reactions, successfully forming various fused, medium-sized, and heterocyclic ring structures.
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