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the claim

Allenes are capable of forming ring structures

the verdict
SUPPORTED
the evidence backs this
Recorded sources
8 sources for · 0 against

Counts group repeated records of the same source within each side. They do not measure evidence strength or source independence.

Is it true that Allenes are capable of forming ring structures?

Yes. Multiple studies demonstrate that allenes readily participate in diverse cyclization and cycloaddition reactions to form various ring structures.

Verdict: SUPPORTED · 8 sources for, 0 against · Last checked

The analysis

The retrieved papers consistently show that allenes can act as versatile intermediates in cyclization, annulation, and cycloaddition reactions, successfully forming various fused, medium-sized, and heterocyclic ring structures.

Evidence for · 8
2019
Demonstrates gold-catalyzed cascade cyclization of allenynes to form fused cyclopropanes and acenaphthenes.
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Ikeuchi, T., Inuki, S., Oishi, S., & Ohno, H. (2019). Gold(I)-Catalyzed Cascade Cyclization Reactions of Allenynes for the Synthesis of Fused Cyclopropanes and Acenaphthenes.. doi.org. https://doi.org/10.1002/anie.201903384

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More for · 7
2019
Details platinum-catalyzed [3+2] and [2+2] cycloaddition reactions of allene derivatives to yield cyclic structures.
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Saha, R., Chatterjee, A., Mondal, S., Pal, P., Chakrabarty, K., & Das, G. (2019). Comparative DFT study on the platinum catalyzed [3 + 2] and [2 + 2] cycloaddition reactions between the derivatives of allene and alkene. doi.org. https://doi.org/10.1016/J.COMPTC.2019.112507

2025
Shows palladium-catalyzed cyclization of allenyl isocyanides to construct medium-sized eight-membered N-heterocycles.
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Zhao, H., Jiang, Y., Zhang, J., Pu, Y., Zeng, S., Ni, B., Shang, Y., & Wang, J. (2025). Construction of Eight-Membered N-Heterocycles via Palladium-Catalyzed Cyclization of Allenyl Isocyanides.. doi.org. https://doi.org/10.1021/acs.orglett.5c02371

2026
Identifies naturally occurring macrocyclic allenes like scabrisporallene containing an allene function embedded in a ring.
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AC, T., H, X., B, G., & JS, D. (2026). Alkyne Cyclizations through Vinyl Cations and Stereoselective Allene Formation by Terpene Synthases.. doi.org. https://doi.org/10.1021/jacs.6c05306

2026
Reports phosphine-catalyzed annulation of allenes for the efficient construction of substituted cyclobutenes.
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SH, S., SN, Y., H, L., ZY, D., Y, J., XP, H., & QA, C. (2026). Phosphine-Catalyzed Unsymmetric [2 + 2] Annulation of Allenyl Phosphonates for Highly Substituted Cyclobutenes.. doi.org. https://doi.org/10.1002/anie.7982002

2026
Details the photochemical cyclization of buta-2,3-dienamides into beta-lactams.
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J, H., MS, B., C, K., & T, B. (2026). Photochemical Cyclization of Tertiary Buta-2,3-dienamides to β-Lactams Upon Triplet Energy Transfer.. doi.org. https://doi.org/10.1002/anie.202525347

2026
Notes that allene intermediates undergo versatile transformations including cyclization to form various heterocycles.
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H, S., DK, B., H, S., & J, W. (2026). Alcohol-Directed Carboamination of Conjugated Enynes.. doi.org. https://doi.org/10.1002/anie.6963888

2026
Describes photocycloaddition reactions of 1,1-dimethylallene to yield bicyclic ring systems.
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L, O., J, Z., N, S., & T, B. (2026). Dearomatization of Aromatic Carbonyl Compounds by Photocycloaddition Reactions to 1,1-Dimethylallene.. doi.org. https://doi.org/10.1021/acs.orglett.6c00429

What does the evidence say?

The retrieved papers consistently show that allenes can act as versatile intermediates in cyclization, annulation, and cycloaddition reactions, successfully forming various fused, medium-sized, and heterocyclic ring structures.

Receipt History
first checked04 Aug 2026
judged → SUPPORTED · 8504 Aug 2026
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