Eigenvalues are used to represent observable physical values in quantum mechanics

Measuring Non-Hermitian Operators via Weak Values. 2014. https://doi.org/10.1103/PhysRevA.92.052120

In quantum theory, a physical observable is represented by a Hermitian operator as it admits real eigenvalues. This stems from the fact that any measuring apparatus that is supposed to measure a physical observable will always yield a real number. However, reality of eigenvalue of some operator does not mean that it is necessarily Hermitian. There are examples of non-Hermitian operators which may admit real eigenvalues under some symmetry conditions. However, in general, given a non-Hermitian operator, its average value in a quantum state is a complex number and there are only very limited methods available to measure it. Following standard quantum mechanics, we provide an experimentally feasible protocol to measure the expectation value of any non-Hermitian operator via weak measurements. The average of a non-Hermitian operator in a pure state is a complex multiple of the weak value of the positive semi-definite part of the non-Hermitian operator. We also prove a new uncertainty relation for any two non-Hermitian operators and show that the fidelity of a quantum state under quantum channel can be measured using the average of the corresponding Kraus operators. The importance of our method is shown in testing the stronger uncertainty relation, verifying the Ramanujan formula and in measuring the product of non commuting projectors.

A Practical Framework for Assessing the Performance of Observable Estimation in Quantum Simulation. 2025. https://doi.org/10.1109/QCE65121.2025.00050

Simulating dynamics of physical systems is a key application of quantum computing, with potential impact in fields such as condensed matter physics and quantum chemistry. However, current quantum algorithms for Hamiltonian simulation yield results that are inadequate for real use cases and suffer from lengthy execution times when implemented on near-term quantum hardware. In this work, we introduce a framework for evaluating the performance of quantum simulation algorithms, focusing on the computation of observables, such as energy expectation values. Our framework provides end-to-end demonstrations of algorithmic optimizations that utilize Pauli term groups based on $k$-commutativity, generate customized Clifford measurement circuits, and implement weighted shot distribution strategies across these groups. These demonstrations span multiple quantum execution environments, allowing us to identify critical factors influencing runtime and solution accuracy. We integrate enhancements into the QED-C Application-Oriented Benchmark suite, utilizing problem instances from the opensource HamLib collection. Our results demonstrate a $\mathbf{2 7. 1} \boldsymbol{\%}$ error reduction through Pauli grouping methods, with an additional 37.6% improvement from the optimized shot distribution strategy. Our framework provides an essential tool for advancing quantum simulation performance using algorithmic optimization techniques, enabling systematic evaluation of improvements that could maximize near-term quantum computers’ capabilities and advance practical quantum utility as hardware evolves.

Measurement in quantum mechanics. https://en.wikipedia.org/wiki/Measurement_in_quantum_mechanics

In quantum physics, a measurement is the testing or manipulation of a physical system to yield a numerical result. A fundamental feature of quantum theory In quantum physics, a measurement is the testing or manipulation of a physical system to yield a numerical result. A fundamental feature of quantum theory is that the predictions it makes are probabilistic. The procedure for finding a probability involves combining a quantum state, which mathematically describes a quantum system, with a mathematical representation of the measurement to be performe In quantum mechanics, each physical system is associated with a Hilbert space, each element of which represents a possible state of the physical system. The approach codified by John von Neumann represents a measurement upon a physical system by a self-adjoint operator on that Hilbert space termed an "observable". These observables play the role of measurable quantities familiar from classical physics: position, momentum, energy, angular momentum and so on. The dimension of the Hilbert space may be infinite, as it is for the space of square-integrable functions on a line, which is used to define the quantum physics of a continuous degree of freedom. Alternatively, the Hilbert space may be finite-dimensional, as occurs for spin degrees of freedom. Many treatments of the theory focus on the finite-dimensional case, as the mathematics involved is somewhat less demanding. Indeed, introductory physics texts on quantum mechanics often gloss over mathematical technicalities that arise for continuous-valued observables and infinite-dimensional Hilbert spaces, such as the distinction between bounded and unbounded operators; questions of convergence (whether the limit of a sequence of Hilbert-space elements also belongs to the Hilbert space), exotic possibilities for sets of eigenvalues, like Cantor sets; and so forth. These issues can be satisfactorily resolved using spectral theory; the present article will avoid them whenever possible.

Weak value beyond conditional expectation value of the pointer readings. 2017. https://doi.org/10.1103/PhysRevA.96.032114

It is argued that a weak value of an observable is a robust property of a single pre- and post-selected quantum system rather than a statistical property. During an infinitesimal time a system with a given weak value affects other systems as if it were in an eigenstate with eigenvalue equal to the weak value. This differs significantly from the action of a system pre-selected only and possessing a numerically equal expectation value. The weak value has a physical meaning beyond a conditional average of a pointer in the weak measurement procedure. The difference between the weak value and the expectation value has been demonstrated on the example of photon polarization. In addition, the weak values for systems pre- and post-selected in mixed states are considered.

arXiv: Almost-periodic time observables for bound quantum systems. https://arxiv.org/abs/0803.3721

Almost-periodic time observables for bound quantum systems It is shown that a canonical time observable may be defined for any quantum system having a discrete set of energy eigenvalues, thus significantly generalising the known case of time observables for periodic quantum systems (such as the harmonic oscillator). The general case requires the introduction of almost-periodic probability operator measures (POMs), which allow the expectation value of any almost-periodic function to be calculated. An entropic uncertainty relation for energy and time is obtained which generalises the known uncertainty relation for periodic quantum systems. While non-periodic quantum systems with discrete energy spectra, such as hydrogen atoms, typically make poor clocks that yield no more than 1 bit of time information, the anisotropic oscillator provides an interesting exception. More generally, a canonically conjugate observable may be defined for any Hermitian operator having a discrete spectrum. Published as: J. Phys. A 41 (2008) 255301 DOI: 10.1088/1751-8113/41/25/255301 arXiv categories: quant-ph

Quantum Filtering and Analysis of Multiplicities in Eigenvalue Spectra. 2026. https://doi.org/10.1103/jch7-734h

Fine-grained spectral properties of quantum Hamiltonians, including both eigenvalues and their multiplicities, provide useful information for characterizing many-body quantum systems as well as for understanding phenomena such as topological order. Extracting such information with small additive error is #BQP-complete in the worst case. In this work, we introduce QFAMES (quantum filtering and analysis of multiplicities in eigenvalue spectra), a quantum algorithm that efficiently identifies clusters of closely spaced dominant eigenvalues and determines their multiplicities under physically motivated assumptions, which allows us to bypass worst-case complexity barriers. QFAMES also enables the estimation of observable expectation values within targeted energy clusters, providing a powerful tool for studying quantum phase transitions and other physical properties. We validate the effectiveness of QFAMES through numerical demonstrations, including its applications to characterizing quantum phases in the transverse-field Ising model and estimating the ground-state degeneracy of a topologically ordered phase in the two-dimensional toric code model. We also generalize QFAMES to the setting of mixed initial states. Our approach offers rigorous theoretical guarantees and significant advantages over existing subspace-based quantum spectral analysis methods, particularly in terms of the sample complexity and the ability to resolve degeneracies.

Quantum computing universal thermalization dynamics in a (2 + 1)D Lattice Gauge Theory.. 2025. https://doi.org/10.1038/s41467-025-60177-7

Simulating non-equilibrium phenomena in strongly-interacting quantum many-body systems, including thermalization, is a promising application of near-term and future quantum computation. By performing experiments on a digital quantum computer consisting of fully-connected optically-controlled trapped ions, we study the role of entanglement in the thermalization dynamics of a Z₂ lattice gauge theory in 2+1 spacetime dimensions. Using randomized-measurement protocols, we efficiently learn a classical approximation of non-equilibrium states that yields the gap-ratio distribution and the spectral form factor of the entanglement Hamiltonian. These observables exhibit universal early-time signals for quantum chaos, a prerequisite for thermalization. Our work, therefore, establishes quantum computers as robust tools for studying universal features of thermalization in complex many-body systems, including in gauge theories.

The quantum theory of the emission and absorption of radiation. 1927. https://doi.org/10.1098/rspa.1927.0039

Abstract The new quantum theory, based on the assumption that the dynamical variables do not obey the commutative law of multiplication, has by now been developed sufficiently to form a fairly complete theory of dynamics. One can treat mathematically the problem of any dynamical system composed of a number of particles with instantaneous forces acting between them, provided it is describable by a Hamiltonian function, and one can interpret the mathematics physically by a quite definite general method. On the other hand, hardly anything has been done up to the present on quantum electrodynamics. The questions of the correct treatment of a system in which the forces are propagated with the velocity of light instead of instantaneously, of the production of an electromagnetic field by a moving electron, and of the reaction of this field on the electron have not yet been touched. In addition, there is a serious difficulty in making the theory satisfy all the requirements of the restricted principle of relativity, since a Hamiltonian function can no longer be used. This relativity question is, of course, connected with the previous ones, and it will be impossible to answer any one question completely without at the same time answering them all. However, it appears to be possible to build up a fairly satisfactory theory of the emission of radiation and of the reaction of the radiation field on the emitting system on the basis of a kinematics and dynamics which are not strictly relativistic. This is the main object of the present paper. The theory is noil-relativistic only on account of the time being counted throughout as a c-number, instead of being treated symmetrically with the space co-ordinates. The relativity variation of mass with velocity is taken into account without difficulty. The underlying ideas of the theory are very simple. Consider an atom interacting with a field of radiation, which we may suppose for definiteness to be confined in an enclosure so as to have only a discrete set of degrees of freedom. Resolving the radiation into its Fourier components, we can consider the energy and phase of each of the components to be dynamical variables describing the radiation field. Thus if Er is the energy of a component labelled r and θr is the corresponding phase (defined as the time since the wave was in a standard phase), we can suppose each Er and θr to form a pair of canonically conjugate variables. In the absence of any interaction between the field and the atom, the whole system of field plus atom will be describable by the Hamiltonian H ═ ΣrEr + Ho equal to the total energy, Ho being the Hamiltonian for the atom alone, since the variables Er, θr obviously satisfy their canonical equations of motion Er ═ — ∂H/∂θr ═ 0, θr ═ ∂H/∂Er ═ 1.