Free electrons do not escape from a conductor spontaneously.

Electric current. https://en.wikipedia.org/wiki/Electric_current

An electric current is a flow of charged particles, such as electrons or ions, through an electrical conductor or space. It is defined as the net rate An electric current is a flow of charged particles, such as electrons or ions, through an electrical conductor or space. It is defined as the net rate at which electric charge flows through a surface. The moving particles are called charge carriers, which may be of several types, depending on the conductor. In electric circuits, the charge carriers are often electrons moving through a wire. In s In a semiconductor it is sometimes useful to think of the current as due to the flow of positive "holes" (the mobile positive charge carriers that are places where the semiconductor crystal is missing a valence electron). This is the case in a p-type semiconductor. A semiconductor has electrical conductivity intermediate in magnitude between that of a conductor and an insulator. This means a conductivity roughly in the range of 10−2 to 104 siemens per centimeter (S⋅cm−1). In the classic crystalline semiconductors, electrons can have energies only within certain bands (i.e. ranges of levels of energy). Energetically, these bands are located between the energy of the ground state, the state in which electrons are tightly bound to the atomic nuclei of the material, and the free electron energy, the latter describing the energy required for an electron to escape entirely from the material. The energy bands each correspond to many discrete quantum states of the electrons, and most of the states with low energy (closer to the nucleus) are occupied, up to a particular band called the valence band. Semiconductors and insulators are distinguished from metals because the valence band in any given metal is nearly filled with electrons under usual operating conditions, while very few (semiconductor) or virtually none (insulator) of them are available in the conduction band, the band immediately above the valence band. The ease of exciting electrons in the semiconductor from the valence band to the conduction band depends on the band gap between the bands. The size of this energy band gap serves as an arbitrary dividing line (roughly 4 eV) between semiconductors and insulators. With covalent bonds, an electron moves by hopping to a neighboring bond. The Pauli exclusion principle requires that the electron be lifted into the higher anti-bonding state of that bond. For delocalized states, for example in one dimension – that is in a nanowire, for every energy there is a state with electrons flowing in one direction and another state with the electrons flowing in the other. For a net current to flow, more states for one direction than for the other direction must be occupied.…