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the claim
Ions do not influence the structure of water beyond the first hydration shell.
the verdict
REFUTED
the evidence says no
Recorded sources
0 sources for · 3 against
Is it true that ions do not influence the structure of water beyond the first hydration shell?
No. Multiple studies demonstrate that ions and solutes significantly influence water structure and hydrogen-bonding networks well beyond the first hydration shell, refuting the claim.
Verdict: REFUTED · 0 sources for, 3 against · Last checked
Evidence against · 3
Distance-dependent excess entropy calculations demonstrate that water retains tetrahedral structuring well beyond the first hydration shell [0].
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Henao, A., Busch, S., Guàrdia, E., Tamarit, J. L., & Pardo, L. C. (2016). The structure of liquid water beyond the first hydration shell. doi.org. https://doi.org/10.1039/c6cp00720a
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More against · 2
Molecular dynamics simulations and friction analysis show that alkali metal ions alter the hydrogen-bond network and viscosity profiles across multiple extended interfacial zones beyond the immediate hydration layer [5].
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M, M., S, C., L, J., RR, N., B, R., & CS, K. (2026). Cation-Induced Interphasial Viscosity Variations on Gold Electrocatalysts in Nanoconfined Aqueous Electrolytes.. doi.org. https://doi.org/10.1021/jacs.6c06065
Atomic force microscopy reveals that structured water around peptide arrays forms multilayered hydration architectures that extend significantly before gradually converging into bulk water [11].
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A, Y., F, P., L, S., DE, C., K, H., K, M., L, P., K, M., T, S., AS, F., T, F., & M, S. (2026). Peptides display multilayered hydration shell substructures dictated by sequence-specific surface chemistry.. doi.org. https://doi.org/10.1038/s41467-026-76923-4
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