The DL notation differs in meaning from the dl notation in stereochemistry
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refutedsupported
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Reference literature confirms that lowercase d, l, and dl denote optical rotation activity, whereas uppercase D, L, and DL denote configuration based on arbitrary conventions.
The notation d, l, and dl (for dextrorotatory and laevorotatory, respectively) is used to designate the sign of optical activity . According to Basic terminology of stereochemistry (IUPAC Recommendations 1996) , this notation is obsolete and its usage is strongly discouraged. The recommended notation uses the prefixes (+), (−), and (±), respectively. Since optical rotation is a distinguishing characteristic of enantiomers, the notation using d, l, and dl as well as the notation using (+), (−), and (±) can be used to distinguish the enantiomers of a chiral molecule. However, without further information, the absolute configuration ( R or S ) of the chiral molecule is indeterminable. Thus, it remains unknown whether the dextrorotatory enantiomer ( d and (+), respectively) is the R enantiomer or the S enantiomer. The notation D, L, and DL is based on the arbitrary convention according to whi