Although ashfall from particulate volcanic plumes is known to be highly electrically charged, little is known about the charging mechanism. We describe experiments designed to investigate the particle charges generated from the fracture of pumice. Small silicate particles were produced in the laboratory during collisions between two samples cut from pumice clasts. The net charge magnitudes detected on these particles are similar to those previously measured on ashfall from volcanic plumes (∼10−5 to 10−6 C kg−1). This net charge is also shown to be the result of a small imbalance between the sums of individual particle charges of both polarities, which are up to several orders of magnitude larger than the net charge. The magnitude of both the net and single polarity specific charges were only weakly affected by changes of relative humidity, but single polarity charges increased steadily with increasing sample impact velocities. The dominant charging process during the experiments was that of material fracture. The charging mechanism is thus interpreted to be fractoemission (the release of nuclear particles from fresh crack surfaces) occurring during the production of the silicate particles. This implies that the electrification of volcanic plumes could be the result of brittle fragmentation of magma or pumice clasts within the upper regions of the conduit and in the jet region of the plume.

Volcanic plume electrification: Experimental investigation of a fracture‐charging mechanism. (2000). doi.org. https://doi.org/10.1029/2000jb900068

The plume from the 2011 eruption of Grímsvötn was highly electrically charged, as shown by the considerable lightning activity measured by the United Kingdom Met Office's low-frequency lightning detection network. Previous measurements of volcanic plumes have shown that ash particles are electrically charged up to hundreds of kilometers away from the vent, which indicates that the ash continues to charge in the plume [R. G. Harrison, K. A. Nicoll, Z. Ulanowski, and T. A. Mather, Environ. Res. Lett. 5, 024004 (2010); H. Hatakeyama J. Meteorol. Soc. Jpn. 27, 372 (1949)]. In this Letter, we study triboelectric charging of different size fractions of a sample of volcanic ash experimentally. Consistently with previous work, we find that the particle size distribution is a determining factor in the charging. Specifically, our laboratory experiments demonstrate that the normalized span of the particle size distribution plays an important role in the magnitude of charging generated. The influence of the normalized span on plume charging suggests that all ash plumes are likely to be charged, with implications for remote sensing and plume lifetime through scavenging effects.

Triboelectric charging of volcanic ash from the 2011 Grímsvötn eruption.. (2013). doi.org. https://doi.org/10.1103/PhysRevLett.111.118501

The origin of electrical activity accompanying volcanic ash plumes is an area of heightened interest in volcanology. However, it is unclear how intense an eruption needs to be to produce lightning flashes as opposed to “vent discharges,” which represent the smallest scale of electrical activity. This study targets 97 carefully monitored plumes <3 km high from Sakurajima volcano in Japan, from June 1 to 7, 2015. We use multiparametric measurements from sensors including a nine‐station lightning mapping array and an infrared camera to characterize plume ascent. Findings demonstrate that the impulsive, high velocity plumes (>55 m/s) were most likely to create vent discharges, whereas lightning flashes occurred in plumes with high volume flux. We identified conditions where volcanic lightning occurred without detectable vent discharges, highlighting their independent source mechanisms. Our results imply that plume dynamics govern the charging for volcanic lightning, while the characteristics of the source explosion control vent discharges.

Impulsive Volcanic Plumes Generate Volcanic Lightning and Vent Discharges: A Statistical Analysis of Sakurajima Volcano in 2015. (2021). doi.org. https://doi.org/10.1029/2020GL092323

Abstract Volcanic plumes become electrically charged, often producing spectacular displays of lightning. Previous research has focused on understanding volcanic lightning, primarily the large electric fields produced by charging of ash particles. Here we report on the previously overlooked phenomenon of volcanic plume electrification in the absence of detectable ash. We present the first in situ vertical profile measurements of charge, thermodynamic, and microphysical properties inside predominantly gaseous plumes directly above an erupting volcano. Our measurements demonstrate that substantial charge (at least ±8,000 pC/m 3 ) is present in gaseous volcanic clouds without detectable ash. We suggest that plume charging may be enhanced by the emission of radon gas from the volcano, which causes ionization. This presents a hitherto unrecognized, but likely to be common, mechanism for charge generation in volcanic plumes, which is expected to modulate plume characteristics and lifetime. This process is currently neglected in recognized mechanisms of volcanic plume electrification.

First In Situ Observations of Gaseous Volcanic Plume Electrification. (2019). doi.org. https://doi.org/10.1029/2019gl082211

The electrification of volcanic plumes has been described intermittently since at least the time of Pliny the Younger and the 79 AD eruption of Vesuvius. Although sometimes disregarded in the past as secondary effects, recent work suggests that the electrical properties of volcanic plumes reveal intrinsic and otherwise inaccessible parameters of explosive eruptions. An increasing number of volcanic lightning studies across the last decade have shown that electrification is ubiquitous in volcanic plumes. Technological advances in engineering and numerical modelling, paired with close observation of recent eruptions and dedicated laboratory studies (shock-tube and current impulse experiments), show that charge generation and electrical activity are related to the physical, chemical, and dynamic processes underpinning the eruption itself. Refining our understanding of volcanic plume electrification will continue advancing the fundamental understanding of eruptive processes to improve volcano monitoring. Realizing this goal, however, requires an interdisciplinary approach at the intersection of volcanology, atmospheric science, atmospheric electricity, and engineering. Our paper summarizes the rapid and steady progress achieved in recent volcanic lightning research and provides a vision for future developments in this growing field.

Volcanic electrification: recent advances and future perspectives.. (2022). doi.org. https://doi.org/10.1007/s00445-022-01591-3

Observations of volcanic lightning made using a lightning mapping array during the 2010 eruption of Eyjafjallajökull allow the trajectory and growth of the volcanic plume to be determined. The lightning observations are compared with predictions of an integral model of volcanic plumes that includes descriptions of the interaction with wind and the effects of moisture. We show that the trajectory predicted by the integral model closely matches the observational data and the model well describes the growth of the plume downwind of the vent. Analysis of the lightning signals reveals information on the dominant charge structure within the volcanic plume. During the Eyjafjallajökull eruption both monopole and dipole charge structures were observed in the plume. By using the integral plume model, we propose the varying charge structure is connected to the availability of condensed water and low temperatures at high altitudes in the plume, suggesting ice formation may have contributed to the generation of a dipole charge structure via thunderstorm-style ice-based charging mechanisms, though overall this charging mechanism is believed to have had only a weak influence on the production of lightning.

Charge structure in volcanic plumes: a comparison of plume properties predicted by an integral plume model to observations of volcanic lightning during the 2010 eruption of Eyjafjallajökull, Iceland.. (2014). doi.org. https://doi.org/10.1007/s00445-014-0828-4

Volcanic lightning detection has proven useful to volcano monitoring by providing information on eruption onset, source parameters, and ash cloud directions. However, little is known about the influence of changing eruptive styles on the generation of charge and electrical discharges inside the eruption column. The 2021 Tajogaite eruption (La Palma, Canary Islands) provided the rare opportunity to monitor variations in electrical activity continuously over several weeks using an electrostatic lightning detector. Here we show that throughout the eruption, silicate particle charging is the main electrification mechanism. Moreover, we find that the type of electrical activity is closely linked to the explosive eruption style. Fluctuations in the electrical discharge rates are likely controlled by variations in the mass eruption rate and/or changes in the eruption style. These findings hold promise for obtaining near real-time information on the dynamic evolution of explosive volcanic activity through electrostatic monitoring in the future.

Explosive eruption style modulates volcanic electrification signals.. (2024). doi.org. https://doi.org/10.1038/s43247-024-01520-6

Most of the nitrogen (N) accessible for life is trapped in dinitrogen (N2), the most stable atmospheric molecule. In order to be metabolized by living organisms, N2 has to be converted into biologically assimilable forms, so-called fixed N. Nowadays, nearly all the N-fixation is achieved through biological and anthropogenic processes. However, in early prebiotic environments of the Earth, N-fixation must have occurred via natural abiotic processes. One of the most invoked processes is electrical discharges, including from thunderstorms and lightning associated with volcanic eruptions. Despite the frequent occurrence of volcanic lightning during explosive eruptions and convincing laboratory experimentation, no evidence of substantial N-fixation has been found in any geological archive. Here, we report on the discovery of a significant amount of nitrate in volcanic deposits from Neogene caldera-forming eruptions, which are well correlated with the concentrations of species directly emitted by volcanoes (sulfur, chlorine). The multi-isotopic composition (δ18O, Δ17O) of the nitrates reveals that they originate from the atmospheric oxidation of nitrogen oxides formed by volcanic lightning. According to these first geological volcanic nitrate archive, we estimate that, on average, about 60 Tg of N can be fixed during a large explosive event. Our findings hint at a unique role potentially played by subaerial explosive eruptions in supplying essential ingredients for the emergence of life on Earth.

Geological evidence of extensive N-fixation by volcanic lightning during very large explosive eruptions.. (2024). doi.org. https://doi.org/10.1073/pnas.2309131121