Three-dimensional aromaticity involves delocalized electron systems in non-planar cage structures
Three-dimensional aromaticity is a recognized chemical concept involving cyclic electron delocalization within non-planar cage structures, such as fullerenes and bowl-shaped hydrocarbons.
The provided papers acknowledge spherical and non-planar aromatic structures like fullerenes and bowl-shaped hydrocarbons, supporting the claim that three-dimensional aromaticity involves delocalized electrons in cage structures.
Merino G, Merino G, Solà M, Fernández I, Foroutan-Nejad C, Lazzeretti P, Frenking G, Anderson HL, Sundholm D, Cossío FP, Petrukhina MA, Wu J, Wu JI, Restrepo A. Aromaticity: Quo Vadis.. 2023. https://doi.org/10.1039/d2sc04998h
Paper [0] highlights that aromaticity encompasses diverse manifestations including spherical and three-dimensional configurations.
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Wang Y. Autodesmotic reactions for general strain energy evaluation in polycyclic aromatic nanocarbons.. 2025. https://doi.org/10.1038/s42004-025-01848-w
Paper [11] discusses bowl-shaped hydrocarbons, fullerenes, and carbon nanobelts, connecting non-planar structures with conjugated pi-electron systems.
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