Thermodynamic phases and states of matter require a minimum number of constituent particles to manifest.
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The retrieved evidence presents conflicting viewpoints, with one source stating that phases of matter are defined in the thermodynamic limit, while another presents a universal formulation of thermodynamics applicable to both large and small systems with few particles.
Phases of matter are sharply defined in the thermodynamic limit. One major challenge of accurately simulating quantum phase diagrams of interacting quantum systems is due to the fact that numerical simulations usually deal with the energy density, a local property of quantum wavefunctions, while identifying different quantum phases generally rely on long-range physics. In this paper we construct generic fully symmetric quantum wavefunctions under certain assumptions using a type of tensor networks: projected entangled pair states, and provide practical simulation algorithms based on them. We find that quantum phases can be organized into crude classes distinguished by short-range physics, which is related to the fractionalization of both on-site symmetries and space-group symmetries. Consequently, our simulation algorithms, which are useful to study long-range physics as well, are expected to be able to sharply determine crude classes in interacting quantum systems efficiently. Examples of these crude classes are demonstrated in half-integer quantum spin systems on the kagome lattice. Limitations and generalizations of our results are discussed.
Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary foundations of thermodynamics, in which entropy and energy are defined and employed beyond equilibrium and without assuming extensivity. The formulation applies to all systems-large and small, with many or few particles-and to all states, whether equilibrium or nonequilibrium, by relying on carefully stated operational definitions and existence principles rather than macroscopic idealizations. Key thermodynamic concepts, including adiabatic availability and available energy, are developed and illustrated using the energy-entropy diagram representation of nonequilibrium states, which provides geometric insight into irreversibility and the limits of work extraction for systems of any size. A substantial part of the paper is devoted to the analysis of entropy transfer in non-work interactions, leading to precise definitions of heat interactions and heat-and-diffusion interactions of central importance in mesoscopic continuum theories of nonequilibrium behavior in simple and complex solids and fluids. As a direct consequence of this analysis, Clausius inequalities and the Clausius statement of the second law are derived in forms explicitly extended to nonequilibrium processes. The resulting framework presents thermodynamics as a universal theory whose concepts apply uniformly to all systems, large and small, and provides a coherent foundation for both teaching and modern applications.