The combustion of hydrogen proceeds via a branched chain reaction mechanism involving free radicals
The combustion of hydrogen is well established as a branched chain reaction mechanism involving key free radical intermediates.
The claim is a specific, well-established fact in combustion chemistry. Retrieved papers [0] and [5] provide direct empirical and kinetic evidence supporting the radical-mediated chain-branching mechanism of hydrogen-oxygen combustion. The remaining papers are tangential, discussing polymer chemistry, atmospheric ozonolysis, or other hydrocarbons.
David Gutman, Garry L. Schott. Shock-Tube Study of Chain Branching during the Induction Period of the Hydrogen—Oxygen Reaction. 1967. https://doi.org/10.1063/1.1840604
Paper [0] investigates the chain-branching kinetics of hydrogen-oxygen combustion, explicitly confirming the role of elementary radical reactions like H + O2 -> OH + O.
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C. K. McLane. Hydrogen Peroxide in the Thermal Hydrogen Oxygen Reaction. II. Reaction of Hydrogen Peroxide with Hydrogen and Chain Initiation in the Hydrogen Oxygen Reaction. 1950. https://doi.org/10.1063/1.1747821
Paper [5] examines the thermal hydrogen-oxygen reaction and supports the conclusion that the reaction proceeds via a radical chain mechanism.
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