Phase transformations during non-isothermal tempering of bainitic or martensitic microstructures obtained after quenching of a medium-carbon low-alloy steel was studied. The microstructures correspond to different locations of an as-quenched large-sized forged ingot used as a die material in the automotive industry. High-resolution dilatometry experiments were conducted to simulate the heat treatment process, as well as to investigate different phenomena occurring during non-isothermal tempering. The microstructures were characterized using optical and scanning electron microscopy. Dilatometry analyses demonstrated that tempering behavior varied significantly from bainitic to martensitic microstructures. Retained austenite, which exists between bainitic ferrite sheaves, decomposes to lower bainite causing a remarkable volume increase. It was found that this decomposition finishes below 386 °C. By contrast, martensite tempering was accompanied with a volume decrease due to the decomposition of medium-carbon martensite to low carbon martensite and carbides.

Automotive steels with ultra-high strength and low alloy content under different heating and cooling processes were investigated. It was shown that those processes exhibited a great influence on the performance of the investigated steels due to the different auto-tempering effects. Compared with the steels under water quenching, there was approximately a 70% increase in the strength and elongation of steels under air cooling, in which the martensite was well-tempered. Although the elongation of the steel with a microstructure composed of ferrite, well-tempered martensite and less-tempered martensite could exceed 15%, the hole expansion ratio was still lower because of the undesirable hardness distribution between the hard phases and the soft phases. It followed from the calculation results based on SEM, TEM and XRD analyses, that for the steel under air cooling, the strengthening mechanism was dominated by the solid solution strengthening and the elongation was determined by the auto-tempering of martensite. Experiments and analyses aimed to explore the strengthening and plasticity mechanisms of auto-tempering steels under the special process of flash heating.

This study employed rapid, short-time duration (1 s) tempering to improve the dynamic performance of high-strength steel (HSS) and ultra-high-strength steel (UHSS), compared to quenched and conventionally (1800 s) tempered microstructures. Rapid tempering significantly improved the Charpy toughness of both steels compared to the conventionally tempered condition at an equivalent tempering parameter (TP) or hardness level. For conventionally tempered conditions, tempered martensite embrittlement was observed within the tempering temperature range of 200–400 °C, whereas rapid tempering exhibited increased Charpy toughness with increasing tempering temperature across all tempering conditions. Dynamic compression experiments indicated that rapid tempering led to improved ductility compared to the conventionally tempered condition at an equivalent TP. This work shows that the same rapid tempering strategy used for HSS is directly transferable to a higher-carbon UHSS and provides the first systematic evidence of improved strength-ductility combinations and cracking resistance under dynamic compression, supported by Kolsky bar experiments.

The present work explores the microstructures and abrasive wear behavior of AISI 410 and AISI 420 martensitic stainless steels after hardening and tempering. Microstructural changes and wear were analyzed using optical microscopy and SEM. Different heat treatments resulted in varying hardness values, with a slight increase at 723 K due to (Fe,Cr)23C6 formation, and a significant reduction at 873 K. SEM and EDS showed AISI 410 had a martensitic structure without notable precipitates, while AISI 420 exhibited coarser and new carbide precipitations after tempering. XRD confirmed martensitic peaks

softening or hardening of a material. Heat treatment techniques include annealing, case hardening, precipitation strengthening, tempering, carburizing Heat treating (or heat treatment) is a group of industrial, thermal and metalworking processes used to alter the physical, and sometimes chemical properties of a material. The most common application is metallurgical. Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, to Proper heat treating requires precise control over temperature, time held at a certain temperature and cooling rate. With the exception of stress-relieving, tempering, and aging, most heat treatments begin by heating an alloy beyond a certain transformation, or arrest (A), temperature. This temperature is referred to as an "arrest" because at the A temperature the metal experiences a period of hysteresis. At this point, all of the heat energy is used to cause the crystal change, so the temperature stops rising for a short time (arrests) and then continues climbing once the change is complete. Therefore, the alloy must be heated above the critical temperature for a transformation to occur. The alloy will usually be held at this temperature long enough for the heat to completely penetrate the alloy, thereby bringing it into a complete solid solution. Iron, for example, has four critical-temperatures, depending on carbon content. Pure iron in its alpha (room temperature) state changes to nonmagnetic gamma-iron at its A2 temperature, and weldable delta-iron at its A4 temperature. However, as carbon is added, becoming steel, the A2 temperature splits into the A3 temperature, also called the austenitizing temperature (all phases become austenite, a solution of gamma iron and carbon) and its A1 temperature (austenite changes into pearlite upon cooling). Between these upper and lower temperatures the pro eutectoid phase forms upon cooling. Because a smaller grain size usually enhances mechanical properties, such as toughness, shear strength and tensile strength, these metals are often heated to a temperature that is just above the upper critical temperature, in order to prevent the grains of solution from growing too large. For instance, when steel is heated above the upper critical-temperature, small grains of austenite form. These grow larger as the temperature is increased. When cooled very quickly, during a martensite transformation, the austenite grain-size directly affects the martensitic grain-size. Larger grains have large grain-boundaries, which serve as weak spots in the structure. The grain size is usually controlled to reduce the probability of… Flame…

which makes the metal harder. Tempering relieves stresses in the metal that were caused by the hardening process; tempering makes the metal less hard while Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the science and the technology of metals, including their production and the engineering of metal components used in products for both consumers and manufacturers. A…

Point defect concentrations in metastable Fe-C alloys Point defect species and concentrations in metastable Fe-C alloys are determined using density functional theory and a constrained free-energy functional. Carbon interstitials dominate unless iron vacancies are in significant excess, whereas excess carbon causes greatly enhances vacancy concentration. Our predictions are amenable to experimental verification; they provide a baseline for rationalizing complex microstructures known in hardened and tempered steels, and by extension other technological materials created by or subjected to extreme environments. Published as: Phys.Rev.Lett 96, 175501 (2006) DOI: 10.1103/PhysRevLett.96.175501 arXiv categories: cond-mat.mtrl-sci