Pre-biotic carbon dioxide on Earth originated primarily from mantle degassing and volcanic outgassing
Geological and geochemical evidence indicates that pre-biotic carbon dioxide on Earth was primarily driven by mantle degassing and volcanic outgassing following events like the Moon-forming impact.
The retrieved papers consistently support the standard geochemical model that Earth's early and pre-biotic atmospheric carbon dioxide was primarily sourced from interior degassing (such as mantle and volcanic outgassing). While some recent papers debate the exact redox state and precise composition (e.g., whether H2/CH4 played a larger initial role in certain Hadean niches), papers directly discussing the origin of early carbon dioxide, like the Moon-forming impact aftermath and long-term carbon cycle degassing models, strongly support mantle and volcanic outgassing as the primary sources.
Mrnjavac N, Wimmer JLE, Brabender M, Schwander L, Martin WF. The Moon-Forming Impact and the Autotrophic Origin of Life.. 2023. https://doi.org/10.1002/cplu.202300270
Paper [5] explains how the Moon-forming impact melted Earth's mantle, causing carbon dioxide to degas into the atmosphere and establish early planetary carbon reservoirs.
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Robert A. Berner. Processes of the Long-Term Carbon Cycle: Degassing of Carbon Dioxide and Methane. 2004. https://doi.org/10.1093/oso/9780195173338.003.0006
Paper [10] outlines the long-term carbon cycle processes, noting that volcanic and mantle degassing are primary mechanisms for restoring carbon dioxide to the Earth's surficial system.
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