Polar coordinates are required to solve the Schrödinger wave equation for the hydrogen atom because of spherical symmetry
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Reference sources establish that the Schrödinger equation for systems with spherical symmetry, such as the hydrogen atom, is most conveniently solved using spherical polar coordinates.
The Schrödinger equation is a partial differential equation that governs the wave function of a non-relativistic quantum-mechanical system. Its discovery
The Schrödinger equation is a partial differential equation that governs the wave function of a non-relativistic quantum-mechanical system. Its discovery was a significant landmark in the development of quantum mechanics. It is named after Erwin Schrödinger, an Austrian physicist, who postulated the equation in 1925 and published it in 1926, forming the basis for the work that resulted in his Nobe
is the 2-body reduced mass of the hydrogen nucleus (just a proton) of mass
m
p
{\displaystyle m_{p}}
and the electron of mass
m
q
{\displaystyle m_{q}}
. The negative sign arises in the potential term since the proton and electron are oppositely charged. The reduced mass in place of the electron mass is used since the electron and proton together orbit each other about a common center of mass, and constitute a two-body problem to solve. The motion of the electron is of principal interest here, so the equivalent one-body problem is the motion of the electron using the reduced mass.
The Schrödinger equation for a hydrogen atom can be solved by separation of variables. In this case, spherical polar coordinates are the most convenient. Thus,