Molecules exist with delta bonds in their ground electronic states.
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Multiple chemical references confirm that transition metal compounds such as chromium(II) acetate, alongside specific rhenium and molybdenum complexes, possess quadruple bonds that incorporate delta bonds in their ground electronic states.
Delta bond
Formation of a δ bond by the overlap of two d orbitals 3D model of a boundary surface of a δ bond in Mo2
In chemistry, a delta bond (δ bond) is a covalent chemical bond, in which four lobes of an atomic orbital on one atom overlap four lobes of an atomic orbital on another atom. This overlap leads to the formation of a bonding molecular orbital with two nodal planes which contain the internuclear axis and go through both atoms.
The Greek letterδ in their name refers to d orbitals, since the orbital symmetry of the δ bond is the same as that of the usual (4-lobed) type of d orbital when seen down the bond axis. This type of bonding is observed in atoms that have occupied d orbitals with low enough energy to participate in covalent bonding, for example, in organometallic species of transition metals. Some rhenium, molybdenum, technetium, and chromium compounds contain a quadruple bond, consisting of oneσ bond, twoπ bonds and one δ bond. In the case of the [Re2Cl8]2- ion in the D4h Point group, the bonding delta interaction is the highest energy bonding interaction, followed by the bonding pi, and sigma interactions. The resultant antibonding delta interaction is the lea
The whole story of the two-electron bond, with the delta bond as a paradigm - PubMed
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## Abstract
It is shown that the delta bond, as found particularly in the Re(2)(6+) and Mo(2)(4+) cores of hundreds of compounds, provides a paradigm for the behavior of two-electron bonds of all types. By control of the angle of twist around the M-M axis, the strength of the bond can be systematically varied. By means of conventional electronic spectroscopy, nuclear magnetic resonance spectroscopy, and two-photon excitation spectroscopy, the entire picture of the manifold of four states for two electrons bonding two atoms, as first described by Coulson and Fischer in 1949, has been confirmed.
## Publication types
Research Support, U.S. Gov't, Non-P.H.S.
## MeSH terms
Electrons
Models, Chemical*
Molybdenum / chemistry*
Rhenium / chemistry*
## Substances
Rhenium
Molybdenum
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### Full Text Sources
- American Chemical Society
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