Molecular formulas can contain decimal subscripts in non-stoichiometric compounds
Molecular formulas for non-stoichiometric compounds often feature decimal subscripts to represent variable elemental compositions.
The claim states that molecular formulas can contain decimal subscripts in non-stoichiometric compounds. Paper [1] discusses the chemistry of non-stoichiometric compounds, and Paper [7] explicitly uses a fractional/decimal subscript in the formula Cu_xV_2O_5 to denote non-stoichiometric insertion. Therefore, the claim is supported.
Koji Kosuge. Chemistry of Non-stoichiometric Compounds. 1994. https://doi.org/10.1093/oso/9780198555551.001.0001
This book details the chemical and structural properties of non-stoichiometric compounds, which feature variable compositions.
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Agbeworvi G, Kumar N, Ponis JD, Hariyani S, Jerla N, Jardali F, Li J, Zaheer W, Handy JV, Ayala JR, Jaye C, Weiland C, Fischer DA, Shamberger PJ, Guo J, Williams RS, Sambandamurthy G, Banerjee S. An Atom-Precise Approach to Damp First-Order Phase Transitions and Its Implications for Neuromorphic Signal Processing.. 2026. https://doi.org/10.1021/jacs.6c02370
This study discusses non-stoichiometric compounds such as Cu_xV_2O_5 containing decimal subscripts representing variable insertion stoichiometries.
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