trustme.bro/r/…
✓ checked
trust me, bro:
here is the receipt.
the claim
Ligand field strength is determined by both electrostatic coulombic effects and covalent bonding interactions
the verdict
SUPPORTED
the evidence backs this
refutedsupported
the weight of evidence
2 sources for · 0 against

The retrieved scientific literature demonstrates that crystal-field and ligand-field interactions are understood through models incorporating both point charge contributions (electrostatic effects) and covalence effects.

Evidence for · 2
1960 · cited by 0
A calculation of the crystalline field strength, $\mathrm{Dq}$, is reported for the case of chrome alum, using the same model and crystal field potential employed by Kleiner and recently determined Hartree-Fock wave functions for the ${\mathrm{Cr}}^{+3}$ ion. On this basis, earlier theoretical attempts at determining, within the framework of crystal field theory, accurate $\mathrm{Dq}$ values are reviewed and analyzed. Particular emphasis is placed on a consideration of reported point charge calculations and Phillips' method of including the effects of orthogonalization of ligand to metal ion wave functions. Our results indicate that the point charge model estimates for $\mathrm{Dq}$ gave good results mostly because they were based on the use of improper $3d$ wave functions for the transition metal cation. Kleiner's result is significantly improved---his wrong sign for $\mathrm{Dq}$ is reversed and a small positive $\mathrm{Dq}$ is obtained---but in such a way as to contradict Phillips conclusions. A discussion is given of the various evidence for the inadequacy of the electrostatic potential theory and some of the necessary modifications are indicated.
See more details
The analysis

rails:sufficiency:supported:single_source:for=1+1p:against=0+0p | v55:sufficiency

More for · 1
2005 · cited by 0
Abstract Systematic behaviors of free-ion and crystal-field interactions are elucidated as a function of N, the number of f electrons in a lanthanide or actinide ion. Experimentally determined values of the free-ion interaction parameters are compared with those calculated based on Hartree-Fock theory. Comparison is also made between the lanthanide series in 4 f N configurations and the actinide series in 5 f N configurations. Variation in intra-ionic electrostatic interaction, spin–orbit coupling, and ion–ligand interaction is analyzed in comparison between the iso-f-electron lanthanide and actinide ions. Based on an exchange-charge model of crystal-field theory, crystal-field parameters of the f-element ions in various crystals are summarized in terms of point charge contribution and covalence effect. A systematic correlation is found between the free-ion parameters and the crystal-field strength. Increase of the crystal-field interaction results in a reduction in the free-ion parameters.
Everything we examined (2)
This check searched the claim as stated. It did not run a separate search for evidence against it.
  1. Calculation of the Crystalline Field Strength: Chrome Alumpeer-reviewedno side taken
  2. Systematics of f-element crystal-field interactionpeer-reviewedno side taken
This receipt carries no identity, shared or not. Sharing publishes your connection to it, not your data.
Check your own claim
Challenge the receipt
trust me, bro: win the argument, pass the class, survive peer review.
This receipt is an automated verdict against our published method · not an opinion about any author or publication.
Terms · Privacy · How verdicts work · Dispute this receipt