Lead(II) iodide exhibits thermochromism
Multiple studies demonstrate that various lead(II) iodide-based hybrid materials and perovskites exhibit thermochromic behavior driven by temperature-dependent structural phase transitions and optical band gap changes.
The retrieved literature contains multiple experimental studies directly documenting thermochromism in lead(II) iodide hybrid crystals and related perovskite structures, supporting the claim without contradictory findings.
Jia-Qi Gan, Zhenhua Xu, Tian Gan, Yan Qin, Zhong‐Xia Wang. Large Phase-Transition Temperature Enhancement Achieved in a Layered Lead Iodide Hybrid Crystal by H/F Substitution.. 2023. https://doi.org/10.1021/acs.inorgchem.3c02485
Paper [0] observes evident thermochromism in a layered hybrid lead iodide crystal.
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Maufort A, Van Landeghem M, Deutsch M, Banks P, La Magna P, Van Hecke K, Cerdá J, Lutsen L, Vanderzande D, Quarti C, Beljonne D, Pillet S, Vandewal K, Van Gompel WTM. Structural rigidity, thermochromism and piezochromism of layered hybrid perovskites containing an interdigitated organic bilayer.. 2025. https://doi.org/10.1039/d4sc06637e
Paper [2] reports thermochromism linked to structural deformability and temperature-dependent photoluminescence in layered hybrid lead perovskites.
Mahboubeh Jamshidi, James M. Gardner. Temperature-dependent excited states for detecting reversible phase transitions in 2D lead( <scp>ii</scp> ) iodide perovskites. 2024. https://doi.org/10.1039/d4dt01210k
Paper [7] investigates reversible phase transitions and resulting optical property changes in 2D lead iodide perovskites.
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