AS REPORTEDno primary record reached; this is what the reporting says
Reference material reports that hydroxide ions can react with alcohols such as ethanol to produce alkoxide ions, demonstrating that hydroxides are capable of ionizing alcohols.
acting as acids. Basic hydroxides, whether solids or in solution, are stored in airtight plastic containers. The hydroxide ion can function as a typical
Hydroxide (occasionally hydroxyl ion) is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, ligand, nucleophile, and catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous soluti
B(OH)3 + H2O ⇌ B(OH)−4 + H+
A variety of oxyanions of boron are known, which, in the protonated form, contain hydroxide groups.
OH− + EtOH ⇌ EtO− + H2O
to produce the ethoxide ion. The pKa for self-dissociation of ethanol is about 16, so the alkoxide ion is a strong enough base. The addition of an alcohol to an aldehyde to form a hemiacetal is an example of a reaction that can be catalyzed by the presence of hydroxide. Hydroxide can also act as a Lewis-base catalyst.
The hydroxide ion is intermediate in nucleophilicity between the fluoride ion F−, and the amide ion NH−2. Ester hydrolysis under alkaline conditions (also known as base hydrolysis)