Fire is sustained by exothermic oxidation-reduction chain reactions
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Reference sources confirm that fire is characterized by the rapid exothermic oxidation of a fuel that sustains itself through a chemical chain reaction.
Fire is the rapid oxidation of a fuel in the exothermic chemical process of combustion, releasing heat, light, and various reaction products. Flames,
Fire is the rapid oxidation of a fuel in the exothermic chemical process of combustion, releasing heat, light, and various reaction products.
Flames, the most visible portion of the fire, are produced in the combustion reaction when the fuel reaches its ignition point temperature. Flames from hydrocarbon fuels consist primarily of carbon dioxide, water vapor, oxygen, and nitrogen. If hot enough, t
Fire is the rapid oxidation of a fuel in the exothermic chemical process of combustion, releasing heat, light, and various reaction products.
Flames, the most visible portion of the fire, are produced in the combustion reaction when the fuel reaches its ignition point temperature. Flames from hydrocarbon fuels consist primarily of carbon dioxide, water vapor, oxygen, and nitrogen. If hot enough, the gases may become ionized to produce plasma. The color and intensity of the flame depend on the type of fuel and composition of the surrounding gases.
Fire, in its most common form, has the potential to result in conflagration, which can lead to permanent physical damage. Fire directly affects land-based ecological systems worldwide. The benefits of fire include stimulating plant growth and maintaining ecological balance. Its harms include hazards to life and property, atmospheric pollution, and water contamination. When fire removes protective vegetation, heavy rainfall can cause soil erosion. The burning of vegetation releases nitrogen into the atmosphere, unlike other plant nutrients such as potassium and phosphorus, which remain in the ash and are quickly recycled into the soil. This loss of nitrogen produces a long-term reduction in the fertility of the soil. However, it can be recovered by nitrogen-fixing plants—some of them of agricultural value, such as clover, peas, and beans, by decomposition of animal waste and corpses
Fire is the rapid oxidation of a fuel in the exothermic chemical process of combustion, releasing heat, light, and various reaction products.
Flames, the most visible portion of the fire, are produced in the combustion reaction when the fuel reaches its ignition point temperature. Flames from hydrocarbon fuels consist primarily of carbon dioxide, water vapor, oxygen, and nitrogen. If hot enough, the gases may become ionized to produce plasma. The color and intensity of the flame depend on the type of fuel and composition of the surrounding gases.
Fire, in its most common form, has the potential to result in conflagration, which can lead to permanent physical damage. Fire directly affects land-based ecological systems worldwide. The benefits of fire include stimulating plant growth and maintaining ecological balance. Its harms include hazards to life and property, atmospheric pollution, and water contamination. When fire removes protective vegetation, heavy rainfall can cause soil erosion. The burning of vegetation releases nitrogen into the atmosphere, unlike other plant nutrients such as potassium and phosphorus, which remain in the ash and are quickly recycled into the soil. This loss of nitrogen produces a long-term reduction in the fertility of the soil. However, it can be recovered by nitrogen-fixing plants—some of them of agricultural value, such as clover, peas, and beans, by decomposition of animal waste and corpses, and by natural phenomena such as lightning.
Fire is one of the four classical elements and has been used throughout human history for purposes that now include cooking, generating heat and light, clearing land for agriculture, signaling, propulsion, smelting, forging, incineration of waste, cremation, rituals, weapons, and destruction, including in warfare.
Various technologies and strategies have been devised to prevent, manage, mitigate, and extinguish fires, with professional firefighters playing a leading role. For example, most home fires start from unattended cooking, although cigarettes are another major cause. Smoke detectors and sprinkler systems greatly reduce harm from home fires.
Fire is a chemical process in which a fuel and an oxidizing agent react, yielding carbon dioxide and water. This process, known as a combustion reaction, does not proceed directly and involves intermediates. Although the oxidizing agent is typically oxygen, other compounds can fulfill the role. For instance, chlorine trifluoride is able to ignite sand.
Fires start when a flammable or a combustible material, in combination with a sufficient quantity of an oxidizer such as oxygen gas or another oxygen-rich compound (though non-oxygen oxidizers exist, such as chlorine), is exposed to a source of heat or ambient temperature above the flash point for the fuel/oxidizer mix, and can sustain a rate of rapid oxidation that produces a chain reaction. This is commonly called the fire tetrahedron. Fire cannot exist without all of these elements in place and in the right proportions. For example, a flammable liquid will start burning only if the fuel and oxygen are in the right proportions. Some fuel-oxygen mixes may require a catalyst, a substance that is not consumed, when added, in any chemical reaction during combustion, but which enables the reactants to combust more readily.
Once ignited, a chain reaction occurs whereby fires can sustain their own heat through the continued release of heat energy during combustion and may propagate, provided there is a continuous supply of an oxidizer and fuel. If the oxidizer is oxygen from the surrounding air, the presence of a force of gravity, or of some similar force caused by acceleration, is necessary to produce convection, which removes combustion products and brings a supply of oxygen to the fire. Without gravity, a fire rapidly surrounds itself with its own combustion products and non-oxidizing gases from the air, which exclude oxygen and extinguish the fire. Because of this,
are both consumed and produced by reaction with the fire’s free radicals. Disrupting the reactions necessary to sustain the flame's combustion, the cycle
Condensed aerosol fire suppression is a particle-based method of fire extinction. It is uses pyrogenic, condensed aerosol fire suppressants to extinguish fires. It is a fire suppression method for class A, B, C, E and F. Similar to other fire-extinguishing agents, it is not applicable to metal fires (class D). Some aerosol-generating compounds (e.g., potassium nitrate-based) produce a corrosive by
Reduction or isolation of fuel
Reduction or…
Condensed aerosol fire suppression is a particle-based method of fire extinction. It is uses pyrogenic, condensed aerosol fire suppressants to extinguish fires. It is a fire suppression method for class A, B, C, E and F. Similar to other fire-extinguishing agents, it is not applicable to metal fires (class D). Some aerosol-generating compounds (e.g., potassium nitrate-based) produce a corrosive by-product that may damage electronic equipment, although later generations have lowered the effect.
Condensed aerosol fire suppression systems employ a fire-extinguishing agent consisting of very finely divided solid particles, suspended in an inert gas. Those superfine aerosol particles are pyrotechnically generated via the combustion of an aerosol-forming agent (AFA) which is stable at room temperature and does not need to be stored in a pressurized container.
Benefits include high performance (3 times more effective than banned Halon 1301, with the aerosol leveraging both cooling, dilution and chemical inhibition), general availability (from plant-size systems to compact and lightweight portable tooling), low toxicity, environmentally friendliness (e.g., 0% ozone depleting potential), non-pressurized systems, and overall cost-effectiveness.
Compared to gaseous suppressants (which emit only gas) and dry chemical suppression agents (which are powder-like particles of a large size – 25–150 micrometers), the National Fire Protection Association defines condensed aerosols as those that release finely divided solids of less than 10 micrometers in diameter.
The solid particulates have a considerably smaller mass median aerodynamic diameter (MMAD) than those of dry chemical suppression agents. The particulates are subject to Brownian motion: the colloid's high diffusive ability and long suspension time mean the microparticles remain airborne significantly longer and leave much less residue within the protected area than alternate (dry or gas) agents. Their large combined surface area efficiently attracts free radicals through surface adsorption.
Condensed aerosols are flooding agents. In closed premises, they are effective regardless of the location and height of the fire. This can be contrasted with dry chemical systems, which must be directly aimed at the flame. In open spaces, they are reasonably effective when targeting the top of the fire, unlike gaseous and dry agents which must be directed at the base of the flames.
The condensed aerosol agent can be delivered by means of mechanical operation, electric operation, or combined electro-mechanical operation.
Wet chemical systems generally found in foam extinguishers must, similarly to dry chemical systems, be sprayed directionally onto the fire.
Hot, condensed aerosol fire-extinguishing agents act on both physical and chemical levels. They leverage four methods to extinguish fires, for they act on the four elements of what is known as the fire tetrahedron. These four means of fire extinction are:
Reduction or isolation of fuel
Reduction or isolation of oxygen
Reduction of heat
Inhibiting the chain reaction of the above components
Condensed aerosols' primary extinguishing mechanism involves the fourth element of the fire tetrahedron by means of chemical reactions with the free radicals of the flame, therefore interfering with the combustion process of the fire.
Heat absorption via endothermic phase changes of the aerosol particles: K2CO3 (solid) -> K2CO3 (liquid) -> K2CO3 (gas)
Heat absorption via endothermic decomposition reaction: 2KHCO3 (solid) -> K2CO3 (solid) + CO2 (gas) + H2O (gas)
Attacking all the elements of the fire tetrahedron, condensed aerosol fire suppression agents are among the more effective flame-extinguishing agents. For example, some condensed aerosol fire suppressants can extinguish a Class B flammable liquid pool fire with 1/5 the amount of Halon 1301 agent or 1/10 the amount of a hydrofluorocarbon or fluoroketone based clean agent gaseous fire suppression system, in terms of kilogram mass of agent per cubic meter.
The extinguishing performance of condensed aerosol fire suppressants is dependent on the density of aerosol particulates in the immediate vicinity of the flame. As with gaseous fire suppression systems, the faster the agent can build around the flame, the more efficient the extinguishing agent is at stopping combustion. The extinguishing and design densities of aerosol fire suppression agents are generally expressed in kilograms per cubic meter (kg/m3). Thus, the efficiency of aerosol extinguishing agents varies depending on a number of factors, such as the location of the aerosol relative to the flame, the proximity of other combustible flammable materials, the type of fuel involved, etc.
Condensed aerosol devices are designed to provide a controlled discharge. The aerosol-forming compound is installed inside of the device, which is then fitted with an electric or mechanical initiator. The electric initiator is interfaced with a fire-detection control unit or panel, which can be remotely operated by physical means such as by cable, operated by hand with a fuse mechanism such as those used in smoke dispensing grenades, or automatic and self-triggering when outfitted with an integral heat-sensing device.
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