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the claim
Enthalpy change of a system can be negative while entropy change is positive
the verdict
COMMON KNOWLEDGE
no citation needed for this one
refutedsupported
the weight of evidence
no sources on either side

The relationship between enthalpy change and entropy change is governed by the Gibbs free energy equation (delta G = delta H - T delta S), and it is a fundamental thermodynamic principle that processes can have a negative enthalpy change and a positive entropy change (which makes them spontaneous at all temperatures).

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The analysis

The claim is a fundamental thermodynamic principle based on the definition of Gibbs free energy (delta G = delta H - T delta S). An exothermic process (negative delta H) accompanied by an increase in disorder (positive delta S) results in a negative delta G, making the process spontaneous. This is a basic textbook definition and everyday scientific fact, rendering it common knowledge that requires no citation.

Everything we examined (12)
  1. Thermostability, Tunability, and Tenacity of RNA as Rubbery Anionic Polymeric Materials in Nanotechnology and Nanomedicine-Specific Cancer Targeting with Undetectable Toxicity.peer-reviewedno side takennot shown: read and judged not to bear on this claim
  2. Discussion on the thermodynamic calculation and adsorption spontaneity re Ofudje et al. (2023)peer-reviewedno side takennot shown: read and judged not to bear on this claim
  3. Adsorption and thermodynamic studies of the corrosion Inhibition effect of Desmodium adscendens (Swartz) extract on carbon steel in 2 M HClpeer-reviewedno side takennot shown: read and judged not to bear on this claim
  4. Aspergillus fumigatus Hsp90 interacts with the main components of the cell wall integrity pathway and cooperates in heat shock and cell wall stress adaptation.peer-reviewedno side takennot shown: read and judged not to bear on this claim
  5. ISOSTERIC HEAT, ENTROPY, AND GIBBS FREE ENERGY OF PUMPKIN SEEDS (Cucurbita moschata)peer-reviewedno side takennot shown: read and judged not to bear on this claim
  6. Atomic‐Level Regulation of Gibbs Free Energy for Thermodynamically Suppressing Vanadium Dissolution in V6O13 Cathode Toward Stable Zinc Storagepeer-reviewedno side takennot shown: read and judged not to bear on this claim
  7. Accumulated Gibbs free energy as a quantitative measure of desorption hysteresis associated with the formation of metastable states.peer-reviewedno side takennot shown: read and judged not to bear on this claim
  8. Continuum Thermodynamics of Constrained Reactive Mixtures.peer-reviewedno side takennot shown: read and judged not to bear on this claim
  9. The evolution of universal adaptations of life is driven by universal properties of matter: energy, entropy, and interaction.peer-reviewedno side takennot shown: read and judged not to bear on this claim
  10. On Enthalpy–Entropy Compensation Characterizing Processes in Aqueous Solutionpeer-reviewedno side takennot shown: read and judged not to bear on this claim
  11. Degradation of tetrabromobisphenol A (TBBA) with calcium hydroxide: a thermo-kinetic analysis.peer-reviewedno side takennot shown: read and judged not to bear on this claim
  12. Why Including Solvation is Paramount: First-Principles Calculations of Electrochemical CO<sub>2</sub> Reduction to CO on a Cu Electrocatalyst.peer-reviewedno side takennot shown: read and judged not to bear on this claim
The paper trail · every fact has a biography
first checked05 Aug 2026
judged → COMMON KNOWLEDGE · 9505 Aug 2026
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