Dissolved carbon dioxide in opened soda remains supersaturated temporarily due to activation energy barriers
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Retrieved physics references explain that opening a soda bottle creates a supersaturated carbon dioxide solution that remains temporarily stable because an energy barrier hinders the formation of initial bubbles through nucleation.
The Diet Coke and Mentos experiment involves dropping Mentos candies into carbonated beverages to produce a fountain. This simple experiment has enjoyed popularity with science teachers and the general public. Studies of the physicochemical processes involved in the generation of the fountain have been largely informed by the physics of bubble nucleation. Herein, we probe the effect of ethanol addition on the Diet Coke and Mentos experiment to explore the impact that beverage surface tension and viscosity have on the heights of fountains achieved. Our results indicate that current descriptions of the effects of surface tension and viscosity are not completely understood. We also extend and apply a previously reported, simplified version of Brunauer-Emmett-Teller theory to investigate kinetic and mechanistic aspects of bubble nucleation on the surface of Mentos candies in carbonated beverages. A combination of this new theory and experiment allows for the estimation that the nucleation sites on the Mentos candy that catalyze degassing are 1-3 μm in size, and that between 50,000 and 300,000 of these sites actively nucleate bubbles on a single Mentos candy. While the methods employed are not highly sophisticated, they have potential to stimulate fresh investigations and insights into bubble nucleation in carbonated beverages.
# Why doesn't soda go flat immediately after opening?
Tags: thermodynamics, everyday-life, physical-chemistry, gas
- Score: 44
- Views: 8216
- Answers: 1
- Answered: yes
- Asked by: Mohammad Athar (681 rep)
- Asked: 2018-01-10
- Edited: 2018-01-11
- Site: physics
## Question
So, soda is under pressure and has gas dissolved in it. But, when you open it, the gas is still dissolved in it. But, if we wait a few hours, the gas has escaped into the atmosphere.
What factors determine the rate at which gas escapes the soda-gas solution?
## Answers
### Answer by John Rennie (score: 45)
When you open the bottle and reduce the pressure you now have a supersaturated solution of carbon dioxide in water so it is energetically favourable for the gas to come out of solution.
However for the gas to come out of solution you have to form a bubble and the mechanism by which this happens is called nucleation. But there is an energy barrier that prevents tiny bubbles from forming, and as a result bubbles will only form when there is something to help them nucleate. For more on this see:
Why does soda fizz when it meets ice?
Why are coke bottles that much fizzier if you shake them?
Anyhow, if
The Business of Fizziness: Find Your Soda's Fizz! | Scientific American
August 16, 2018
4 min read
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# The Business of Fizziness: Find Your Soda's Fizz!
A bubbly science activity from Science Buddies
By Science Buddies& Megan Arnett
How does your soda fizz? Use some science to find out how to gasses are hiding in soda--and how you can make them escape more quickly.
George Retseck
Key conceptsChemistryReactionsSupersaturationNucleation
IntroductionYou’ve probably seen the reaction that happens when you add Mentos candy to a bottle of diet soda. The resulting eruption can be powerful enough to be dangerous, and is the source of many online videos! Although many people are familiar with this reaction, few of them understand the science behind why it takes place. Mentos plus soda is not actually a chemical reaction but rather a physical one called nucleation. In this activity we will explore nucleation in soda at a smaller scale by adding some unusual ingredients to our soda!
BackgroundCarbonated drinks, such as soda, are in a state of supersaturation, meaning soda is completely saturated with carbon dioxide (CO2). Once any solution is supersaturated
# Why can't CO$_2$ mix back with the liquid after a soda bottle has been shaken?
Tags: pressure, atmospheric-science
- Score: 17
- Views: 9845
- Answers: 4
- Answered: yes
- Asked by: Lazer (866 rep)
- Asked: 2010-11-25
- Edited: 2015-01-15
- Site: physics
## Question
If you shake a soda bottle before opening it, and then open it, you get the fizz.
That is the compressed CO2 releasing to the atmosphere which is at comparatively low pressure value.
Two questions (related)
Why does shaking a bottle make the compresses gases un-dissolve?
Why can't the gases dissolve back into the liquid?
## Answers
### Answer by Vagelford (score: 5 [ACCEPTED])
This is what I think that happens. The bottles with the soda have the liquid inside under pressure. Under these conditions you have an amount of CO$_2$ dissolved in the liquid. If you shake it then it will make some bubbles but not a lot and it will return to the previous state. If you don't disturb the liquid and open the bottle, then the pressure will drop to atmospheric levels. The dissolved CO$_2$ in the liquid is in a grater concentration that the liquid can hold for that pressure. But there are no evaporation seeds for the bubble
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