Within the de Sitter ambient space framework, the two different bases of the one-particle Hilbert space of the de Sitter group algebra are presented for the scalar case. Using field operator algebra and its Fock space construction in this formalism, we discuss the existence of asymptotic states in de Sitter QFT under an extension of the adiabatic hypothesis and prove the Fock space completeness theorem for the massive scalar field. We define the quantum state in the limit of future and past infinity on the de Sitter hyperboloid in an observer-independent way. These results allow us to examine the existence of the S-matrix operator for de Sitter QFT in ambient space formalism, a question which is usually obscure in spacetime with a cosmological event horizon for a specific observer. Some similarities and differences between QFT in Minkowski and de Sitter spaces are discussed.