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the claim
Calculated harmonic infrared frequencies depend systematically on the size of the basis set
the verdict
SUPPORTED
the evidence backs this
refutedsupported
the weight of evidence
2 sources for · 0 against

Calculated harmonic infrared frequencies depend systematically on the size of the basis set, converging toward the complete basis set limit as larger and more flexible basis sets are employed.

Evidence for · 2
2003 · cited by 99
Paper 0 investigates the basis set convergence of harmonic vibrational frequencies and infrared intensities, showing that calculated values approach the complete basis set limit systematically as the basis set quality improves.
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The analysis

The claim states that calculated harmonic infrared frequencies depend systematically on the basis set size. Papers 0 and 2 explicitly discuss how calculated vibrational frequencies vary systematically with basis set size and converge toward the complete basis set limit. Therefore, the evidence supports the claim.

More for · 1
2011 · cited by 28
Paper 2 demonstrates the calculation of harmonic and anharmonic frequencies of formamide using a hierarchy of polarization-consistent basis sets (pc-n) to extrapolate to the complete basis set limit.
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first checked04 Aug 2026
judged → SUPPORTED · 8804 Aug 2026
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