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the claim

Alcohols and carbonyls differ in their reactivity towards phosphorus pentachloride

the verdict

SUPPORTED

the evidence backs this

confidence 84/100

Alcohols and carbonyls react differently with phosphorus pentachloride: alcohols are converted into alkyl chlorides, whereas ketones and other carbonyl compounds yield alkenyl chlorides or undergo chlorination via distinct pathways.

Evidence for · 2

The reaction of tertiary alcohols with phosphorus pentachloride

1976 · cited by 27

Paper 0 establishes that phosphorus pentachloride reacts with tertiary alcohols to produce tertiary chlorides.

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More for · 1

Synthesis and applications of alkenyl chlorides (vinyl chlorides): a review.

2026 · cited by 0

Paper 8 notes that phosphorus pentachloride reacts with ketones (carbonyls) to yield alkenyl chlorides.

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first checked01 Aug 2026

judged → SUPPORTED · 8401 Aug 2026

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