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A resonating valence bond state describes a quantum superposition of singlet pairings in magnetic materials
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Multiple peer-reviewed physics sources and reference texts establish that a resonating valence bond state consists of a quantum superposition of singlet pairings among electron spins in magnetic materials.

Evidence for · 10
2017 · cited by 67
Since its proposal by Anderson, resonating valence bonds (RVB) formed by a superposition of fluctuating singlet pairs have been a paradigmatic concept in understanding quantum spin liquids. Here, we show that excitations related to singlet breaking on nearest-neighbour bonds describe the high-energy part of the excitation spectrum in YbMgGaO4, the effective spin-1/2 frustrated antiferromagnet on the triangular lattice, as originally considered by Anderson. By a thorough single-crystal inelastic neutron scattering study, we demonstrate that nearest-neighbour RVB excitations account for the bulk of the spectral weight above 0.5 meV. This renders YbMgGaO4 the first experimental system where putative RVB correlations restricted to nearest neighbours are observed, and poses a fundamental question of how complex interactions on the triangular lattice conspire to form this unique many-body state. The signature of short range resonating valence bonds (RVB) to understand quantum spin liquids is yet to be explored. Here, Liet al. observe the putative RVB correlations restricted to nearest neighbours in YbMgGaO4, responsible for the high-energy spin excitations.
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More for · 9
2010 · cited by 53
We use Monte Carlo simulations to study properties of Anderson’s resonating-valence-bond (RVB) spin-liquid state on the square lattice (i.e., the equal superposition of all pairing of spins into nearest-neighbor singlet pairs) and compare with the classical dimer model (CDM). The latter system also corresponds to the ground state of the Rokhsar-Kivelson quantum dimer model at its critical point. We find that, although spin-spin correlations decay exponentially in the RVB, four-spin valence-bond-solid correlations are critical, qualitatively like the well-known dimer-dimer correlations of the CDM, but decaying more slowly (as 1/r with α ≈ 1.20, compared with α = 2 for the CDM). We also compute the distribution of monomer (defect) pair separations, which decay by a larger exponent in the RVB than in the CDM. We further study both models in their different winding-number sectors and evaluate the relative weights of different sectors. Like the CDM, all the observed RVB behaviors can be understood in the framework of a mapping to a “height” model characterized by a gradient-squared stiffness constant K . Four independent measurements consistently show a value KRVB ≈ 1.6KCDM, with the same kinds of numerical evaluations of KCDM giving results in agreement with the rigorously known value KCDM = π/16. The background of a nonzero winding-number gradient W/L introduces spatial anisotropies and an increase in the effective K , both of which can be understood as a consequence of anharmonic terms in the height-model free energy, which are of relevance to the recently proposed scenario of “Cantor deconfinement” in extended quantum dimer models. In addition to the standard case of short bonds only, we also studied ensembles in which fourth-neighbor (bipartite) bonds are allowed at a density controlled by a tunable fugacity, resulting (as expected) in a smooth reduction of K .
Polynomial representation for multipartite entanglement of resonating valence bond ladders
2023 · cited by 1
A resonating valence bond (RVB) state of a lattice of quantum systems is a potential resource for quantum computing and communicating devices. It is a superposition of singlet, i.e., dimer, coverings - often restricted to nearest-neighbour ones - of the lattice. We develop a polynomial representation of multipartite quantum states to prove that RVB states on ladder lattices possess genuine multipartite entanglement. The multipartite entanglement of doped RVB states and RVB states that are superposed with varying weights for singlet coverings of ladder lattices can both be detected by using this technique.
cited by 0
In condensed matter physics, a quantum spin liquid is a phase of matter that can be formed by interacting quantum spins in certain magnetic materials In condensed matter physics, a quantum spin liquid is a phase of matter that can be formed by interacting quantum spins in certain magnetic materials. Quantum spin liquids (QSL) are generally characterized by their long-range quantum entanglement, fractionalized excitations, and absence of ordinary magnetic order. The quantum spin liquid state was first proposed by physicist Phil Anderson in 1973 I… To build a ground state without magnetic moment, valence bond states can be used, where two electron spins form a spin 0 singlet due to the antiferromagnetic interaction. If every spin in the system is bound like this, the state of the system as a whole has spin 0 too and is non-magnetic. The two spins forming the bond are maximally entangled, while not being entangled with the other spins. If all spins are distributed to certain localized static bonds, this is called a valence bond solid (VBS). There are two things that still distinguish a VBS from a spin liquid: First, by ordering the bonds in a certain way, the lattice symmetry is usually broken, which is not the case for a spin liquid. Second, this ground state lacks long-range entanglement. To achieve this, quantum mechanical fluctuations of the valence bonds must be allowed, leading to a ground state consisting of a superposition of many different partitionings of spins into valence bonds. If the partitionings are equally distributed (with the same quantum amplitude), there is no preference for any specific partitioning ("valence bond liquid"). This kind of ground state wavefunction was proposed by P. W. Anderson in 1973 as the ground state of spin liquids and is called a resonating valence bond (RVB) state. These states are of great theoretical interest as they are proposed to play a key role in high-temperature superconductor physics. The valence bonds do not have to be formed by nearest neighbors only and their distributions may vary in different materials. Ground states with large contributions of long range valence bonds have more low-energy spin excitations, as those valence bonds are easier to break up. On breaking, they form two free spins. Other excitations rearrange the valence bonds, leading to low-energy excitations even for short-range bonds. Something very special about spin liquids is that they support exotic excitations, meaning excitations with fractional quantum numbers. A prominent example is the excitation of spinons which are neutral in charge and carry spin S = 1 / 2 {\displaystyle S=1/2} .…
2020 · cited by 0
Solving strongly coupled gauge theories in two or three spatial dimensions is of fundamental importance in several areas of physics ranging from high-energy physics to condensed matter. On a lattice, gauge invariance and gauge invariant (plaquette) interactions involve (at least) four-body interactions that are challenging to realize. Here we show that Rydberg atoms in configurable arrays realized in current tweezer experiments are the natural platform to realize scalable simulators of the Rokhsar-Kivelson Hamiltonian --a 2D U(1) lattice gauge theory that describes quantum dimer and spin-ice dynamics. Using an electromagnetic duality, we implement the plaquette interactions as Rabi oscillations subject to Rydberg blockade. Remarkably, we show that by controlling the atom arrangement in the array we can engineer anisotropic interactions and generalized blockade conditions for spins built of atom pairs. We describe how to prepare the resonating valence bond and the crystal phases of the Rokhsar-Kivelson Hamiltonian adiabatically, and probe them and their quench dynamics by on-site measurements of their quantum correlations. We discuss the potential applications of our Rydberg simulator to lattice gauge theory and exotic spin models.
2005 · cited by 0
We propose a new class of ground states for doped Mott insulators in the electron second-quantization representation. They are obtained from a bosonic resonating valence bond (RVB) theory of the t-J model. At half filling, the ground state describes spin correlations of the S=1/2 Heisenberg model very accurately. Its spin degrees of freedom are characterized by RVB pairing of spins, the size of which decreases continuously as holes are doped into the system. Charge degrees of freedom emerge upon doping and are described by twisted holes in the RVB background. We show that the twisted holes exhibit an off diagonal long range order (ODLRO) in the pseudogap ground state, which has a finite pairing amplitude, but is short of phase coherence. Unpaired spins in such a pseudogap ground state behave as free vortices, preventing superconducting phase coherence. The existence of nodal quasiparticles is also ensured by such a hidden ODLRO in the ground state, which is non-Fermi-liquid-like in the absence of superconducting phase coherence. Two distinct types of spin excitations can also be constructed. The superconducting instability of the pseudogap ground state is discussed and a d-wave superconducting ground state is obtained. This class of pseudogap and superconducting ground states unifies antiferromagnetism, pseudogap, superconductivity, and Mott physics into a new state of matter.
2011 · cited by 0
We investigate the ground state of the $d^1$ spin-orbital model for triply degenerate $t_{2g}$ orbitals on a triangular lattice which unifies intrinsic frustration of spin and orbital interactions with geometrical frustration. Using full or Lanczos exact diagonalization of finite clusters we establish that the ground state of the spin-orbital model which interpolates between the superexchange and direct exchange interactions on the bonds is characterized by valence-bond correlations. In the absence of Hund's exchange the model describes a competition between various possible valence-bond states. By considering the clusters with open boundary conditions we demonstrate that orbital interactions are always frustrated, but this frustration is removed by pronounced spin singlet correlations which coexist with supporting them dimer orbital correlations. Such local configurations contribute to the disordered ground states found for the clusters with periodic boundary conditions which interpolate between a highly resonating, dimer-based, entangled spin-orbital liquid phase, and a valence-bond state with completely static spin-singlet states. We argue that these states are also realized for the infinite lattice and anticipate that pronounced transitions between different regimes found for particular geometries will turn out to smooth crossovers in the properties of the spin-orbital liquid in the thermodynamic limit. Finally, we provide evidence that the resonating spin-orbital liquid
2011 · cited by 0
We investigate the ground state of the $d^1$ spin-orbital model for triply degenerate $t_{2g}$ orbitals on a triangular lattice which unifies intrinsic frustration of spin and orbital interactions with geometrical frustration. Using full or Lanczos exact diagonalization of finite clusters we establish that the ground state of the spin-orbital model which interpolates between the superexchange and direct exchange interactions on the bonds is characterized by valence-bond correlations. In the absence of Hund's exchange the model describes a competition between various possible valence-bond states. By considering the clusters with open boundary conditions we demonstrate that orbital interactions are always frustrated, but this frustration is removed by pronounced spin singlet correlations which coexist with supporting them dimer orbital correlations. Such local configurations contribute to the disordered ground states found for the clusters with periodic boundary conditions which interpolate between a highly resonating, dimer-based, entangled spin-orbital liquid phase, and a valence-bond state with completely static spin-singlet states. We argue that these states are also realized for the infinite lattice and anticipate that pronounced transitions between different regimes found for particular geometries will turn out to smooth crossovers in the properties of the spin-orbital liquid in the thermodynamic limit. Finally, we provide evidence that the resonating spin-orbital liquid
2002 · cited by 0
We show that the resonating valence bond (RVB) state of the t-J Hamiltonian can be described within an effective boson-fermion model. We derive a boson-fermion Hamiltonian which describes the lowest order coupling between holons and spinon waves. The RVB order parameter determines a hybridization between the both types of excitations. The effective Hamiltonian is investigated within the lowest order self-consistent conserving diagrammatic approximation. We compare our approach with the phenomenological boson--fermion model (BFM) that is believed to describe the pseudogap phase.
1972 · cited by 0
One- and two-particle reduced density matrices have been calculated for a ``resonating'' Heitler-London wavefunction, in a system which is a finite model of a two-dimensional square planar lattice structure (4×4 net of one-electron atoms with Born-von Karman boundary conditions). The Heitler-London wavefunction describes the electronic ground state of a system with a single narrow half-filled band (the Mott insulator). Various measures of electron correlation (pair correlation functions, etc.) are defined and calculated. The intent of these calculations is to provide ``empirical'' guidelines for many-body methods for calculation of Green's functions for one and two particles (reduced density matrices are initial values for the respective Green's functions). Results show that the Heitler-London description is incompatible with several assumptions and widely used models for the Mott insulator. In particular it is found that (a) pair correlations in the Heitler-London ground state remain local even when ``resonance'' of an extremely large number of valence-bond structures occurs; the long range antiferromagnetic ordering obtained in several models of the Mott insulator (the ``two-sublattice'' or ``different bands for different spins'' models) does not occur. (b) The density matrix for the Heitler-London state does not exhibit a BCS type ``pair condensation'', as has been conjectured to describe the Mott insulator in some recent work. Our results strongly suggest that if the Heit
Everything we examined (10) — 9 independent sources
This check searched the claim as stated. It did not run a separate search for evidence against it.
  1. Quantum spin liquidreferenceno side taken
  2. Nearest-neighbour resonating valence bonds in YbMgGaO4peer-reviewedno side taken
  3. Properties of Resonating-Valence-Bond Spin Liquids and Critical Dimer Modelspeer-reviewedno side taken
  4. Polynomial representation for multipartite entanglement of resonating valence bond ladderspeer-reviewedno side taken
  5. Emerging Two-Dimensional Gauge Theories in Rydberg Configurable Arrayspeer-reviewedno side taken
  6. Bosonic resonating valence bond wave function for doped Mott insulatorspeer-reviewedno side taken
  7. Spin-orbital resonating valence bond liquid on a triangular lattice: Evidence from finite-cluster diagonalizationreferencesame source L10no side taken
  8. Spin-orbital resonating valence bond liquid on a triangular lattice: Evidence from finite-cluster diagonalizationpeer-reviewedsame source L10no side taken
  9. On the relation between the boson-fermion model and RVB statepeer-reviewedno side taken
  10. Reduced Density Matrices for Valence Bond Wavefunctions. III. Density Matrices for the 4×4 Square Planar Netpeer-reviewedno side taken
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