A conceptual diurnal model accurately describes atmospheric ozone profiles
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Peer-reviewed validation literature reports that global atmospheric chemistry model simulations accounting for diurnal variability show good agreement with observed vertical ozone profiles.
Abstract. We developed a set of solar zenith angle, latitude- and
altitude-dependent scaling factors to account for the diurnal variability in
ozone (O3) and nitrogen dioxide (NO2) when comparing Stratospheric
Aerosol and Gas Experiment (SAGE) III/ISS observations to observations from
other times of day. The scaling factors are calculated as a function of
solar zenith angle from the four-dimensional output of a global atmospheric chemistry model simulation of 2017–2020 that shows good agreement with
observed vertical profiles. Using a global atmospheric chemistry model
allows us to account for both chemically and dynamically driven variability.
Both year-specific scale factors and a multi-year monthly climatology are
available to decrease the uncertainty in inter-instrument comparisons and
allow consistent comparisons between observations from different times of
day. We describe the variability in the diurnal scale factors as a function
of space and time. The quasi-biennial oscillation (QBO) appears to be a
contributing factor to interannual variability in the NO2 scaling
factors, leading to differences between years that switch sign with
altitude. We show that application of these scaling factors improves the
comparison between SAGE III/ISS and OSIRIS NO2 and between SAGE III/ISS and OMPS LP, OSIRIS, and ACE-FTS O3 observations. The comparisons between SAGE III/ISS O3 for sunrise or sunset vs. Microwave Limb Sounder (MLS) daytime or nighttime observations are also more consistent when we apply the diurnal scaling factors. There is good agreement between SAGE III/ISS V5.2
ozone and correlative measurements, with differences within 5 % between
20 and 50 km when corrected for diurnal variability. Similarly, the SAGE III/ISS V5.2 NO2 agreement with correlative measurement is mostly within
10 %. While the scale factors were designed for use with SAGE III/ISS
observations, they can easily be applied to other observation
intercomparisons as well.
The scaling factors are calculated as a function of solar zenith angle from the four-dimensional output of a global atmospheric chemistry model simulation of 2017–2020 that shows good agreement with observed vertical profiles. Using a global atmospheric chemistry model allows us to account for both chemically and dynamically driven variability. Both year-specific scale factors and a multi-year monthly climatology are available to decrease the uncertainty in inter-instrument comparisons and allow consistent comparisons between observations from different times of day. We describe the variability in the diurnal scale factors as a function of space and time.
2.1.2 Optical Spectrograph and InfraRed Imaging System (OSIRIS) The OSIRIS instrument (Llewellyn et al., 2004) is a limb sounder that was launched in February 2001 on board the Odin satellite (Murtagh et al., 2002). OSIRIS provides vertical profiles of ozone, aerosol, and NO 2 with approximately 2 km vertical resolution. Variations in SZA along the line of sight can impact retrievals of species with strong diurnal cycles such as NO 2 for occultation and limb measurements (Mclinden et al., 2006; Brohede et al., 2007).
The reported accuracy of the OSIRIS V6.1 NO 2 retrieval is ±10 % when accounting for the diurnal variability in NO 2 along the line of sight (Sioris et al., 2017) and 5 % above 21 km for the ozone v5.07 retrieval (Adams et al., 2014). 2.1.3 Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) The ACE-FTS (Bernath et al., 2005; Bernath, 2017) measures trace gas profiles from the SCISAT-1 satellite. ACE-FTS, like SAGE III/ISS, uses solar occultation to take measurements during sunrise and sunset.
(2014) found reasonable agreement between the simulated O 3 diurnal cycle at Mauna Loa, Hawaii, with microwave ozone profiling radiometer (MWR) observations at most levels, with most of the modeled and measured values agreeing to within 1.5 % of the midnight value. However, between 39 and 43 km, the morning vs. night differences in the MWR observations are 2 %–3 % higher than in the model. In addition, the diurnal peak relative to midnight is overestimated in the model compared to the MWR observations for 35–39 km in June–August. Frith et al.
5 Summary and conclusions We used the GEOS-GMI global atmospheric chemistry model simulation to develop diurnal scale factors for 2017–2020 to account for differences between SAGE III/ISS and other observations due to the diurnal cycles of NO 2 and O 3 . These scale factors provide a straightforward method for comparing observations from different times of day as they provide the ratios of O 3 and NO 2 at each solar zenith angle to their values at sunrise and sunset based on the simulated diurnal
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